[(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester

Base Information

Chemical Name:[(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester
CAS No.:142979-99-5
Molecular Formula:C₂₂H₃₂NO₉P
Molecular Weight:485.471
Hs Code.:

[(<i>Z</i>)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester

Synonyms:[(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester

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Chemical Property of [(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester

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Technology Process of [(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester

There total 7 articles about [(Z)-3-(2-acetoxymethyl-[1,3]dioxolan-2-yl)-propylideneamino]-diethoxyphosphoryl-acetic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 54214-74-3
1-acetoxy-5-hexen-2-one ethylene glycol ketal

: 142979-99-5
[3-(2-Acetoxymethyl-[1,3]dioxolan-2-yl)-prop-(E)-ylideneamino]-(diethoxy-phosphoryl)-acetic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / NaIO₄, OsCl₃ / H₂O; 2-methyl-propan-2-ol / 0.5 h / Ambient temperature

2: MgSO₄ / diethyl ether / 0.67 h / Ambient temperature

With sodium periodate; osmium (III) chloride; magnesium sulfate; In diethyl ether; water; tert-butyl alcohol;
DOI:10.1021/jo00046a030

Reference yield:

: 54244-69-8
tert-butoxycarbonylamino-acetic acid benzyl ester

: 142979-99-5
[3-(2-Acetoxymethyl-[1,3]dioxolan-2-yl)-prop-(E)-ylideneamino]-(diethoxy-phosphoryl)-acetic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / N-bromosuccinimide / CCl₄ / 15 °C / Irradiation

2: 61 percent / CH₂Cl₂ / Ambient temperature

3: 85 percent / HCl (gas) / CH₂Cl₂ / Ambient temperature

4: MgSO₄ / diethyl ether / 0.67 h / Ambient temperature

With hydrogenchloride; N-Bromosuccinimide; magnesium sulfate; In tetrachloromethane; diethyl ether; dichloromethane;
DOI:10.1021/jo00046a030

Reference yield:

: 100-39-0
benzyl bromide

: 142979-99-5
[3-(2-Acetoxymethyl-[1,3]dioxolan-2-yl)-prop-(E)-ylideneamino]-(diethoxy-phosphoryl)-acetic acid benzyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1) 20percent aq. solution of Cs₂CO₃ / 1) MeOH, water, pH 7.0, 2) DMF, 5 h

2: 100 percent / N-bromosuccinimide / CCl₄ / 15 °C / Irradiation

3: 61 percent / CH₂Cl₂ / Ambient temperature

4: 85 percent / HCl (gas) / CH₂Cl₂ / Ambient temperature

5: MgSO₄ / diethyl ether / 0.67 h / Ambient temperature

With hydrogenchloride; N-Bromosuccinimide; magnesium sulfate; caesium carbonate; In tetrachloromethane; diethyl ether; dichloromethane;
DOI:10.1021/jo00046a030