α-H,4-H-tetradecachlorotriphenylmethane

Base Information

• Chemical Name: α-H,4-H-tetradecachlorotriphenylmethane
• CAS No.: 79839-44-4
• Molecular Formula: C₁₉H₂Cl₁₄
• Molecular Weight: 726.567
• Mol file: 79839-44-4.mol

Synonyms:α-H,4-H-tetradecachlorotriphenylmethane

Chemical Property of α-H,4-H-tetradecachlorotriphenylmethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-H,4-H-tetradecachlorotriphenylmethane

There total 6 articles about α-H,4-H-tetradecachlorotriphenylmethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

1,2,4,5-tetrachlorobenzene (95-94-3) + α-chlorobis(pentachlorophenyl)methane (33119-38-9) → α-H,4-H-tetradecachlorotriphenylmethane (79839-44-4)

Guidance literature:

With aluminium trichloride; at 150 ℃; for 1.5h;

DOI:10.1055/s-1986-31479

Reference yield: 57.6%

ammonium α-H-tetradecachlorotriphenylmethane-4-carboxylate (79839-42-2) → α-H,4-H-tetradecachlorotriphenylmethane (79839-44-4)

Guidance literature:

at 330 - 335 ℃; for 0.5h;

DOI:10.1021/jo00341a015

Reference yield:

4-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,5,6-tetrachlorobenzoic acid (79839-41-1) → α-H,4-H-tetradecachlorotriphenylmethane (79839-44-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 96.7 percent / NH₃(gas) / diethyl ether / 0.5 h

2: 57.6 percent / 0.5 h / 330 - 335 °C

With ammonia; In diethyl ether;

DOI:10.1021/jo00341a015

upstream raw materials:

1,2,4,5-tetrachlorobenzene

α-chlorobis(pentachlorophenyl)methane

ammonium α-H-tetradecachlorotriphenylmethane-4-carboxylate

pentachlorobenzene

Downstream raw materials:

αH-tetradecachloro-4-nitrotriphenylmethane

4-H-tetradecachlorotriphenylmethyl radical

Tetra-n-butylammonium 4H-tetradecachlorotriphenylmethide

αH,α'H-icosachloro-α,α,α'-triphenyl-p-xylene