BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)

Base Information

Chemical Name:BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)
CAS No.:425370-68-9
Molecular Formula:C48H45 Cl N4 O2 P2 Ru
Molecular Weight:908.37
Hs Code.:
Mol file:425370-68-9.mol

Synonyms:BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)

Suppliers and Price of BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)

Chemical Property:

PSA：89.12000
LogP:8.94670

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II)

There total 1 articles about BIS(TRIPHENYLPHOSPHINO)[BIS(3,5-DIMETHYLPYRAZOL-1-YL)ACETATO]CHLORORUTHENIUM(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 331943-38-5
bis(3,5-dimethylpyrazol-1-yl)acetic acid

: 425370-68-9
[Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)Cl(PPh₃)2]

Guidance literature:: With potassium tert-butoxide; In tetrahydrofuran; byproducts: KCl, triphenylphosphine; under Ar; KOC(CH3)3 added to soln. of the acetic acid derivative in THF,mixt. stirred at room temp. for 1 h, Ru complex added to suspn., stirre d at room temp. for 0.5 h; evapd. under vac., residue washed with water and Et2O, dried under vac.;
DOI:10.1002/1099-0682(200203)2002:3<671::AID-EJIC671>3.0.CO;2-V

Reference yield: 97.0%

: 600-18-0
2-Oxobutyric acid

: 425370-68-9
[Ru(bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(PPh₃)2]

: 563-68-8
thallium(I) acetate

: 791601-97-3
bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2 O(1),O(2)-2-oxobutyrato)

Guidance literature:: In dichloromethane; byproducts: TlCl, P(C6H5)3; (inert atm.), Ru complex, slight excess of TlOAc and excess of carboxylic acid stirred in CH2Cl2 at room temp. for 2 h; filtered (Celite), dried (vac.), pptd.(CH2Cl2/pentane), elem. anal.;
DOI:10.1002/ejic.200300816

Reference yield: 96.0%

: 110-86-1
pyridine

: 425370-68-9
[Ru(bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(PPh₃)2]

: 1068652-99-2
[RuCl(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh₃)(pyridine)]

Guidance literature:: In pyridine; dichloromethane; byproducts: P(C6H5)3; (Ar); addn. of pyridine to CH2Cl2 soln. of ruthenium compd., stirring atroom temp. for 3 d; IR monitoring, concg., addn. of pentane, filtration, drying in vac., elem. anal.;
DOI:10.1021/ic8000224