bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

Base Information

Chemical Name:bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)
CAS No.:791601-92-8
Molecular Formula:C₃₂H₃₃N₄O₄PRu
Molecular Weight:669.682
Hs Code.:

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Chemical Property of bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

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Technology Process of bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

There total 1 articles about bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 425370-68-9
[Ru(bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(PPh₃)2]

: 563-68-8
thallium(I) acetate

: 791601-92-8
bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

Guidance literature:: In dichloromethane; byproducts: TlCl, P(C6H5)3; (inert atm.), Ru complex mixed with slight excess of Tl carboxylate in CH2Cl2, stirred at room temp. for 60 h; filtered (Celite), dried (vac.), pptd.(CH2Cl2/pentane), elem. anal.;
DOI:10.1002/ejic.200300816

Reference yield: 99.0%

: 75-09-2
dichloromethane

: 791601-92-8
bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

: 75-05-8,26809-02-9
acetonitrile

: [Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(acetonitrile)(acetate-κ1O)]*dichloromethane

Guidance literature:: In acetonitrile; (Ar); stirring CH3CN soln. of ruthenium compd. at room temp. for 5 h; IR monitoring, concg., addn. of pentane, filtration, drying in vac., elem. anal.;
DOI:10.1021/ic8000224

Reference yield: 97.0%

: 791601-92-8
bis(3,5-dimethylpyrazol-1-yl)acetato ruthenium(II) PPh3 (κ2-O(1),O(1')-acetato)

: 201230-82-2
carbon monoxide

: 1068653-05-3
[Ru(bis(3,5-dimethylpyrazol-1-yl)acetato)(PPh3)(CO)(acetate-κ1O)]

Guidance literature:: In dichloromethane; (Ar); flushing CH2Cl2 soln. of ruthenium compd. with CO under stirring at room temp. for 2 h; IR monitoring, concg., addn. of pentane, filtration, drying in vac., elem. anal.;
DOI:10.1021/ic8000224