dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III)

Base Information

• Chemical Name: dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III)
• CAS No.: 132510-32-8
• Molecular Formula: C₄₃H₃₄Cl₃O₂P₂Ru
• Molecular Weight: 852.118
• Mol file: 132510-32-8.mol

Synonyms:dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III)

Chemical Property of dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III)

There total 2 articles about dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III) (132510-32-8)

Guidance literature:

In dichloromethane; Addn. of m-chloroperbenzoic acid to a soln. of Ru-complex under N2, stirring (0.5 h, room temp.).; Evapn. of solvent in vac., filtn., washing (aq. NaOH), H2O), dissolving of dried product in CH2Cl2, column chromy. (silica gel, benzene), slow evapn., elem. anal.;

DOI:10.1039/DT9900003389

Reference yield:

C43H34Cl3NO3P2Ru → dichloro(m-chlorobenzoato-κO,O')bis(triphenylphosphine)ruthenium(III) (132510-32-8)

Guidance literature:

In dichloromethane; UV-irradiation;

DOI:10.1016/j.ica.2013.04.042

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

3-chloro-benzenecarboperoxoic acid