N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Base Information

Chemical Name:N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide
CAS No.:209679-62-9
Molecular Formula:C₅₀H₆₄N₆O₁₁
Molecular Weight:925.092
Hs Code.:

Synonyms:N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Suppliers and Price of N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

There total 2 articles about N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 194213-77-9
5-([2,2':6',2''-terpyridin]-4'-yloxy)pentan-1-amine

: 209679-61-8
N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-5-nitroisophthalimide monocarboxylic acid

: 209679-62-9
N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Guidance literature:: N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-5-nitroisophthalimide monocarboxylic acid; With benzotriazol-1-ol; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; at 25 ℃; for 1h;

5-([2,2':6',2''-terpyridin]-4'-yloxy)pentan-1-amine; In N,N-dimethyl-formamide; Further stages.;
DOI:10.1021/ja001401h

Reference yield:

: 73585-90-7
5-nitroisophthalic monoacyl chloride

: 209679-62-9
N-{tris[(2-tert-butoxycarbonyl)ethyl]methyl}-N'-[4'-oxa-(2,2':6',2''-terpyridinyl)]-5-nitroisophthalimide

Guidance literature:: Multi-step reaction with 2 steps

1.1: 54 percent / Et₃N / tetrahydrofuran / 12 h / -5 °C

2.1: dicyclohexylcarbodiimide; 1-hydroxybenzotriazole / dimethylformamide / 1 h / 25 °C

2.2: 84 percent / dimethylformamide

With benzotriazol-1-ol; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja001401h