Technology Process of methyl 1-O-benzyl-α-D,L-erythro-hex-2-ulopyranosid-5-ulose
There total 8 articles about methyl 1-O-benzyl-α-D,L-erythro-hex-2-ulopyranosid-5-ulose which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
osmium(VIII) oxide; silver perchlorate;
In
tetrahydrofuran; water;
for 12h;
Ambient temperature;
DOI:10.1016/0040-4020(82)85036-9
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 98 percent / NaOH / dimethylsulfoxide / 5.75 h
2: 61 percent / POCl3 / 1 h / Ambient temperature
3: 93.5 percent / LAH / diethyl ether / Ambient temperature
4: 86 percent / Br2 / diethyl ether / 0.5 h / -45 - -35 °C
5: 100 percent / 1percent H2SO4 / acetone / 2 h / Ambient temperature
6: 85 percent / silver oxide / diethyl ether / 8 h / Ambient temperature
7: 71 percent / AgClO4, osmium tetroxide / tetrahydrofuran; H2O / 12 h / Ambient temperature
With
sodium hydroxide; osmium(VIII) oxide; lithium aluminium tetrahydride; sulfuric acid; bromine; silver perchlorate; silver(l) oxide; trichlorophosphate;
In
tetrahydrofuran; diethyl ether; water; dimethyl sulfoxide; acetone;
DOI:10.1016/0040-4020(82)85036-9
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 61 percent / POCl3 / 1 h / Ambient temperature
2: 93.5 percent / LAH / diethyl ether / Ambient temperature
3: 86 percent / Br2 / diethyl ether / 0.5 h / -45 - -35 °C
4: 100 percent / 1percent H2SO4 / acetone / 2 h / Ambient temperature
5: 85 percent / silver oxide / diethyl ether / 8 h / Ambient temperature
6: 71 percent / AgClO4, osmium tetroxide / tetrahydrofuran; H2O / 12 h / Ambient temperature
With
osmium(VIII) oxide; lithium aluminium tetrahydride; sulfuric acid; bromine; silver perchlorate; silver(l) oxide; trichlorophosphate;
In
tetrahydrofuran; diethyl ether; water; acetone;
DOI:10.1016/0040-4020(82)85036-9
