2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Base Information

Chemical Name:2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
CAS No.:461699-81-0
Molecular Formula:C13H20 B N O3
Molecular Weight:249.118
Hs Code.:2934999090
European Community (EC) Number:695-776-6
DSSTox Substance ID:DTXSID00590350
Wikidata:Q82484067
Mol file:461699-81-0.mol

Synonyms:461699-81-0;2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline;4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER;4-Amino-3-methoxyphenylboronic acid pinacol ester;(4-AMINO-3-METHOXYPHENYL)BORONIC ACID PINACOL ESTER;2-methoxy-4-(tetramethyl-1,3,2-dioxaborolan-2-yl)aniline;SCHEMBL178289;DTXSID00590350;KEMUFKXFCINKAA-UHFFFAOYSA-N;MFCD06795657;AKOS015960112;AB29185;AS-36360;CS-0041457;EN300-7362064;A872279;4-amino-3-methoxyphenylboronic acid pinacol ester, AldrichCPR;4-Amino-3-methoxyphenylboronic acid, pinacol ester, AldrichCPR;2-methoxy-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenylamine;2-methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-aniline

Suppliers and Price of 2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Amino-3-methoxyphenylboronic acid, pinacol ester
250mg
$ 75.00

TRC
4-Amino-3-methoxyphenylboronic acid, pinacol ester
1g
$ 170.00

Sigma-Aldrich
4-Amino-3-methoxyphenylboronic acid, pinacol ester Aldrich
1g
$ 223.00

Crysdot
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 95+%
10g
$ 485.00

Crysdot
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 95+%
5g
$ 307.00

Chemenu
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 95+%
5g
$ 303.00

Chemenu
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 95+%
10g
$ 531.00

Chemenu
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 95+%
1g
$ 78.00

Biosynth Carbosynth
4-Amino-3-methoxyphenylboronic acid, pinacol ester
2 g
$ 300.00

Biosynth Carbosynth
4-Amino-3-methoxyphenylboronic acid, pinacol ester
1 g
$ 180.00

Total 22 raw suppliers

Chemical Property of 2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:113-116°C
Boiling Point:373.1°Cat760mmHg
Flash Point:179.4°C
PSA：53.71000
Density:1.08g/cm³
LogP:2.15780
Storage Temp.:under inert gas (nitrogen or Argon) at 2–8 °C
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:249.1536237
Heavy Atom Count:18
Complexity:293

Purity/Quality:

97% ^*data from raw suppliers

4-Amino-3-methoxyphenylboronic acid, pinacol ester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC(=C(C=C2)N)OC

Technology Process of 2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

There total 7 articles about 2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 461699-81-0
2-methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Guidance literature:: With sodium hydroxide; In water; toluene; pH=8;

In water; toluene; at 20 ℃;

Reference yield: 69.0%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 121-43-7,63156-11-6
Trimethyl borate

: 226713-38-8
benzhydryliden-(4-bromo-2-methoxyphenyl)-amine

: 461699-81-0
2-methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Guidance literature:: benzhydryliden-(4-bromo-2-methoxyphenyl)-amine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; hexane; at -85 ℃; for 1h;

2,3-dimethyl-2,3-butane diol; With sodium hydroxide; sulfuric acid; more than 3 stages;

Reference yield: 36.0%

: 59557-91-4
4-bromo-2-methoxyaniline

: 73183-34-3
bis(pinacol)diborane

: 461699-81-0
2-methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Guidance literature:: With 1,1'-bis-(diphenylphosphino)ferrocene; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In dimethyl sulfoxide; at 80 ℃; for 2h;
DOI:10.1016/j.bmcl.2010.12.047