(6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene

Base Information

• Chemical Name: (6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene
• CAS No.: 345659-42-9
• Molecular Formula: C₃₀H₃₄O₂Si
• Molecular Weight: 454.684
• Mol file: 345659-42-9.mol

Synonyms:(6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene

Chemical Property of (6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene

There total 1 articles about (6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

dimethyl(phenyl)silyl lithium (3839-31-4) + 4,4'-dimethoxydiphenylacetylene (2132-62-9) + 3-chloroprop-1-ene (107-05-1) → (6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene (345659-42-9)

Guidance literature:

dimethyl(phenyl)silyl lithium; 4,4'-dimethoxydiphenylacetylene; With zirconocene dichloride; In tetrahydrofuran; at -78 - 20 ℃; for 4h;

3-chloroprop-1-ene; With copper(l) chloride; In tetrahydrofuran; at 20 ℃; Further stages.;

DOI:10.1021/ja003334x

Reference yield: 97.0%

(6E)-6,7-bis(4-methoxyphenyl)-5-methyl-5-phenyl-5-siladeca-1,6,9-triene (345659-42-9) → (2E,5Z)-2,3-bis(4-methoxyphenyl)-1-methyl-1-phenyl-1-silacycloocta-2,5-diene

Guidance literature:

With Grubbs catalyst first generation; In dichloromethane; at 20 ℃;

DOI:10.1021/ja003334x

upstream raw materials:

dimethyl(phenyl)silyl lithium

4,4'-dimethoxydiphenylacetylene

3-chloroprop-1-ene