4-(Methoxymethoxy)phenylboronic acid

Base Information

Chemical Name:4-(Methoxymethoxy)phenylboronic acid
CAS No.:162662-27-3
Molecular Formula:C8H11BO4
Molecular Weight:181.984
Hs Code.:2931900090
DSSTox Substance ID:DTXSID50376287
Nikkaji Number:J2.318.415J
Wikidata:Q72490236
Mol file:162662-27-3.mol

Synonyms:162662-27-3;4-(METHOXYMETHOXY)PHENYLBORONIC ACID;(4-(Methoxymethoxy)phenyl)boronic acid;[4-(methoxymethoxy)phenyl]boronic Acid;Boronic acid, [4-(methoxymethoxy)phenyl]-;4-methoxymethoxyphenylboronic acid;SCHEMBL3658523;DTXSID50376287;4-Methoxymethoxyphenylboranic acid;MERYVSUVKVVJMP-UHFFFAOYSA-N;4-methoxymethoxy-phenylboronic acid;4-methoxymethyloxyphenyl boronic acid;MFCD03412067;(4-(Methoxymethoxy)phenyl)boronicacid;4-(methoxymethoxy)-phenylboronic acid;AKOS006279745;AB14354;BS-21636;CS-0030290;FT-0605425;Boronic acid, B-[4-(methoxymethoxy)phenyl]-;[4-(methoxymethoxy)phenyl]-boronic acid, AldrichCPR

Suppliers and Price of 4-(Methoxymethoxy)phenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-(Methoxymethoxy)phenylboronicAcid
50mg
$ 60.00

TRC
4-(Methoxymethoxy)phenylboronicAcid
10mg
$ 45.00

SynQuest Laboratories
4-(Methoxymethoxy)phenylboronic acid
25 g
$ 944.00

SynQuest Laboratories
4-(Methoxymethoxy)phenylboronic acid
5 g
$ 276.00

Matrix Scientific
4-(Methoxymethyl)phenylboronic acid 97%
1g
$ 10.00

Crysdot
(4-(Methoxymethoxy)phenyl)boronicacid 95+%
1g
$ 85.00

Crysdot
(4-(Methoxymethoxy)phenyl)boronicacid 95+%
5g
$ 240.00

Crysdot
(4-(Methoxymethoxy)phenyl)boronicacid 95+%
10g
$ 420.00

Crysdot
(4-(Methoxymethoxy)phenyl)boronicacid 95+%
25g
$ 720.00

AOBChem
4-(Methoxymethoxy)phenylboronic acid 97%
50g
$ 734.00

Total 40 raw suppliers

Chemical Property of 4-(Methoxymethoxy)phenylboronic acid

Chemical Property:

Vapor Pressure:0.000657mmHg at 25°C
Refractive Index:1.518
Boiling Point:346.27 °C at 760 mmHg
PKA:8.62±0.16(Predicted)
Flash Point:163.218 °C
PSA：58.92000
Density:1.195 g/cm³
LogP:-0.65090
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:182.0750390
Heavy Atom Count:13
Complexity:134

Purity/Quality:

97% ^*data from raw suppliers

4-(Methoxymethoxy)phenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi,Xn
Statements: 22-41
Safety Statements: 26-39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=C(C=C1)OCOC)(O)O

Technology Process of 4-(Methoxymethoxy)phenylboronic acid

There total 7 articles about 4-(Methoxymethoxy)phenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 98491-29-3
1-iodo-4-(methoxymethoxy)benzene

: 162662-27-3
4-(methoxymethoxy)phenylboronic acid

Guidance literature:: 1-iodo-4-(methoxymethoxy)benzene; With n-butyllithium; Triisopropyl borate; In tetrahydrofuran; diethyl ether; hexane; at -100 - -78 ℃; for 1h; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; diethyl ether; hexane; at -78 ℃; for 1h; Saturated solution;
DOI:10.1021/np100407n

Reference yield: 71.0%

: 25458-45-1
p-methoxymethoxybromobenzene

: 162662-27-3
4-(methoxymethoxy)phenylboronic acid

Guidance literature:: p-methoxymethoxybromobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 5h;

With hydrogenchloride; In tetrahydrofuran; hexane; water; at 0 ℃; for 0.5h;
DOI:10.1080/00397910500466074

Reference yield: 67.7%

: 121-43-7,63156-11-6
Trimethyl borate

: 25458-45-1
p-methoxymethoxybromobenzene

: 162662-27-3
4-(methoxymethoxy)phenylboronic acid

Guidance literature:: p-methoxymethoxybromobenzene; With n-butyllithium; In tetrahydrofuran; at -40 ℃; for 2h;

Trimethyl borate; In tetrahydrofuran; at 20 ℃; for 8h;