1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Base Information

Chemical Name:1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate
CAS No.:1351530-55-6
Molecular Formula:C₄₇H₄₁N₂O₄*ClO₄
Molecular Weight:797.304
Hs Code.:

Synonyms:1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Suppliers and Price of 1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

There total 2 articles about 1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 131543-46-9,107-22-2
Glyoxal

: 1351530-49-8
(4S,5S)-5-amino-2,2,4-triphenyl-1,3-dioxacyclohexane

: 1351530-55-6
1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Guidance literature:: With formaldehyd; perchloric acid; In water; toluene; Inert atmosphere;
DOI:10.1016/j.jorganchem.2011.04.001

Reference yield:

: 119-61-9
benzophenone

: 73473-94-6
(1S,2S)-(+)-2-Amino-1-phenyl-1,3-propandiol-hydrobromid

: 1351530-55-6
1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

Guidance literature:: Multi-step reaction with 2 steps

1: aluminum (III) chloride / acetonitrile / 264 h / Inert atmosphere; Cooling with ice

2: formaldehyd; perchloric acid / water; toluene / Inert atmosphere

With aluminum (III) chloride; formaldehyd; perchloric acid; In water; toluene; acetonitrile;
DOI:10.1016/j.jorganchem.2011.04.001

Reference yield: 48.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 75-09-2
dichloromethane

: 1351530-55-6
1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolium perchlorate

: chloro(η4-1,5-cyclooctadiene)(1,3-di-[(4S,5S)-2,2,4-triphenyl-1,3-dioxacyclohex-5-yl]imidazolin-2-ylidene)rhodium(I)*0.66CH2Cl2

Guidance literature:: With lithium tert-butanolate; In tetrahydrofuran; under Ar; soln. of Rh compd. cooled to -78°C, added Li compd., stirred for 30 min, added perchlorate, stirred at room temp. for 3 d; solvent removed (vac.), ppt. purified by column chromy., dried (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2011.04.001