[2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

Base Information

Chemical Name:[2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane
CAS No.:80398-93-2
Molecular Formula:C₁₉H₃₀OSSi
Molecular Weight:334.598
Hs Code.:

Synonyms:[2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

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Chemical Property of [2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

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Technology Process of [2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

There total 7 articles about [2-((Z)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29193-71-3
methyl 4-(phenylsulfanyl)butanoate

: 80398-93-2
[(1S,2S)-2-((E)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NCS, 2.) t-BuOK / 1.) CCl₄, reflux, 2.) THF, from -20 deg C to room temp.

2: 86 percent / LiAlH₄ / diethyl ether / Heating

3: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

4: 1.) t-BuOK / 1.) THF

With N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034

Reference yield:

: 63196-76-9,116500-60-8,116500-62-0,144407-72-7
Methyl trans-2-phenylthiocyclopropanecarboxylate

: 80398-93-2
[(1S,2S)-2-((E)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / LiAlH₄ / diethyl ether / Heating

2: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

3: 1.) t-BuOK / 1.) THF

With lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034

Reference yield:

: 108-98-5
thiophenol

: 80398-93-2
[(1S,2S)-2-((E)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) LiH, 2.) H₂SO₄ / 1.) THF, HMPA, room temp.

2: 1.) NCS, 2.) t-BuOK / 1.) CCl₄, reflux, 2.) THF, from -20 deg C to room temp.

3: 86 percent / LiAlH₄ / diethyl ether / Heating

4: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

5: 1.) t-BuOK / 1.) THF

With N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; sulfuric acid; potassium tert-butylate; lithium hydride; In diethyl ether;
DOI:10.1021/jo00343a034