METHANE (13C,D4)

Base Information

• Chemical Name: METHANE (13C,D4)
• CAS No.: 2644-20-4
• Molecular Formula: ¹³CD4
• Molecular Weight: 21
• Mol file: 2644-20-4.mol

Synonyms:Methane-13C-d4(7CI);Methane (13CD4);

Chemical Property of METHANE (13C,D4)

Chemical Property:

• Melting Point: -183 °C(lit.)
• Boiling Point: -161 °C(lit.)
• PSA: 0.00000
• Density: 0.55 (vs air)
• LogP: 0.63610

Purity/Quality:

99%, ^*data from raw suppliers

METHANE (13C,D4) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+
• Hazard Codes: F+
• Statements: 12
• Safety Statements: 16-38-33-9

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHANE (13C,D4)

There total 2 articles about METHANE (13C,D4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon dioxide (1111-72-4) → tetradeuterio-[13C]methane (2644-20-4) + [13C,2H4]methyl alcohol (32479-98-4) + [13C]Carbon monoxide (1641-69-6)

Guidance literature:

With deuterium; at 170 ℃; under 750.075 Torr; Reagent/catalyst; Catalytic behavior;

DOI:10.1021/jacs.9b10873

Reference yield:

methane (6532-48-5) → deuterio-[13C]methane (2758-34-1) + dideuterio-[13C]methane (66067-61-6) + trideuterio-[13C]methane (66067-62-7) + tetradeuterio-[13C]methane (2644-20-4)

Guidance literature:

With AlCl(x)F(3-x) x:0.05-0.30;; benzene-d6; at 70 ℃; for 24h; under 517.552 Torr; Reagent/catalyst; Catalytic behavior;

DOI:10.1002/cctc.201701327

Reference yield:

tetradeuterio-[13C]methane (2644-20-4)

Guidance literature:

at 674.9 ℃; Irradiation;

DOI:10.1021/j100105a028

upstream raw materials:

methane

carbon dioxide

Refernces

• 1、 Calvo, Beatriz,Braun, Thomas,Kemnitz, Erhard. "Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminum Chlorofluoride". . p. 403 - 406. Retrieved 2017/12/26.