Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

Base Information

Chemical Name:Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester
CAS No.:120027-69-2
Molecular Formula:C₂₄H₂₆O₆S₄
Molecular Weight:538.731
Hs Code.:

Synonyms:Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

There total 1 articles about Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 75-15-0,12122-00-8
carbon disulfide

: 28224-73-9
1,3:4,6-di-O-benzylidene-D-mannitol

: 74-88-4
methyl iodide

: 120027-69-2
Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

Guidance literature:: carbon disulfide; 1,3:4,6-di-O-benzylidene-D-mannitol; With sodium hydride; In tetrahydrofuran;

methyl iodide; In tetrahydrofuran;
DOI:10.1016/j.carres.2006.06.022

Reference yield: 77.0%

: 120027-69-2
Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

: 151061-72-2
1,3:4,6-di-O-benzylidene-2,5-dideoxy-1,5-thio-L-iditol

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; at 80 ℃;
DOI:10.1016/j.carres.2006.06.022

Reference yield:

: 120027-69-2
Dithiocarbonic acid S-methyl ester O-((4R,5R,4'R,5'R)-5'-methylsulfanylthiocarboxyoxy-2,2'-diphenyl-[4,4']bi[[1,3]dioxanyl]-5-yl) ester

: 913619-28-0
1,3:4,6-di-O-benzylidene-2,5-dideoxy-1,5-[[(2R,3R)-2,4-O-benyzlidene-2,4-dihydroxy-3-(sulfooxy)butyl]sulfoniumylidene]-L-iditol inner salt

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / Bu₃SnH; AIBN / toluene / 80 °C

2: 79 percent / 1,1,1,3,3,3-hexafluoroisopropanol; K₂CO₃ / 48 h / 75 °C

With 2,2'-azobis(isobutyronitrile); 1,1,1,3',3',3'-hexafluoro-propanol; tri-n-butyl-tin hydride; potassium carbonate; In toluene;
DOI:10.1016/j.carres.2006.06.022