NITRONIUM HEXAFLUOROPHOSPHATE

Base Information

• Chemical Name: NITRONIUM HEXAFLUOROPHOSPHATE
• CAS No.: 19200-21-6
• Molecular Formula: F6NO2P
• Molecular Weight: 190.97
• Hs Code.: 28269080
• Mol file: 19200-21-6.mol

Synonyms:Nitroniumhexafluorophosphate98%;

Chemical Property of NITRONIUM HEXAFLUOROPHOSPHATE

Chemical Property:

• Appearance/Colour: Colorless or white crystals
• Vapor Pressure: 5.13E-06mmHg at 25°C
• Refractive Index: 1.601
• Boiling Point: 381.3°C at 760 mmHg
• Flash Point: 184.4°C
• PSA: 47.73000
• Density: 1.35g/cm³
• LogP: 2.96880
• Sensitive.: Hygroscopic
• Solubility.: Soluble in dichloromethane and nitroethane.

Purity/Quality:

99%, ^*data from raw suppliers

Nitronium hexafluorophosphate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): CT
• Hazard Codes: C,T
• Statements: 34-14
• Safety Statements: 45-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Nitronium hexafluorophosphate is a nitrating reagent used in the nitration of alkanes such as methane, ethane, propane, n-butane, isobutane, neopentane and cyclohexane.

Technology Process of NITRONIUM HEXAFLUOROPHOSPHATE

There total 7 articles about NITRONIUM HEXAFLUOROPHOSPHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bromine trifluoride (7787-71-5) + phosphorous + bromine (7726-95-6) + dinitrogen tetraoxide (10544-72-6) → nitronium hexafluorophosphate (19200-21-6)

Guidance literature:

In not given; treating red P with Br2; addn. of N2O4 and BrF3;;

DOI:10.1039/JR9500001050

Reference yield:

phosphorus pentafluoride (7647-19-0,874483-74-6) + nitrylfluoride (10022-50-1) → nitronium hexafluorophosphate (19200-21-6)

Guidance literature:

In not given; react. of PF5 with NO2F;;

DOI:10.1039/JR9540001119

Reference yield:

phosphorus pentafluoride (7647-19-0,874483-74-6) + dinitrogen pentoxide (10102-03-1) → nitronium hexafluorophosphate (19200-21-6)

Guidance literature:

With hydrogen fluoride; In nitromethane; react. of PF5 with a soln. of HF and N2O5 in nitromethane;;

DOI:10.1021/ja01483a016

upstream raw materials:

nitrylfluoride

bromine trifluoride

bromine

dinitrogen tetraoxide

Downstream raw materials:

lithium hexafluorophosphate