Nitrogen pentoxide

Base Information

• Chemical Name: Nitrogen pentoxide
• CAS No.: 10102-03-1
• Molecular Formula: N2O5
• Molecular Weight: 108.01
• UNII: 6XB659ZX2W
• DSSTox Substance ID: DTXSID90143672
• Wikipedia: Dinitrogen pentoxide,Dinitrogen_pentoxide
• Wikidata: Q408458
• Mol file: 10102-03-1.mol

Synonyms:dinitrogen pentoxide;nitrogen pentoxide

Chemical Property of Nitrogen pentoxide

Chemical Property:

• Melting Point: 30°
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 100.87000
• Density: 1.786g/cm³
• LogP: 0.43280
• Water Solubility.: very soluble chloroform without appreciable decomposition; less soluble CCl4 [MER06]
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 107.98072110
• Heavy Atom Count: 7
• Complexity: 71.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

DINITROGEN PENTAOXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Other Nitrogen Compounds
• Canonical SMILES: [N+](=O)([O-])O[N+](=O)[O-]
• Physical properties: Colorless hexagonal crystal; volatile solid; density 1.642 g/cm3 at 18°C; melts at 30°C; decomposes at 47°C; soluble in water forming nitric acid; soluble in chloroform with some decomposition.
• Uses: As nitrating agent in chloroform solution.

Technology Process of Nitrogen pentoxide

There total 71 articles about Nitrogen pentoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nitrogen (7727-37-9) + oxygen (80937-33-3) → ozone (10028-15-6) + dinitrogen pentoxide (10102-03-1)

Guidance literature:

With nitrogen; In neat (no solvent); Electrochem. Process; reaction in O2-N2 mixtures for different periods of time, yields depend on reaction time and N2 amount;;

Reference yield:

nitrogen (7727-37-9) + oxygen (80937-33-3) → nitrogen(II) oxide (10102-43-9) + ozone (10028-15-6) + dinitrogen pentoxide (10102-03-1)

Guidance literature:

silent electric discharges at 380-700 °C;

Reference yield:

nitrogen (7727-37-9) + oxygen (80937-33-3) → nitrogen(II) oxide (10102-43-9) + Nitrogen dioxide (10102-44-0) + ozone (10028-15-6) + dinitrogen pentoxide (10102-03-1) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In gas; byproducts: NO3; description of processes in a barrier discharge during electrosynthesisof O3; investigation of effect of power of discharge, working frequencyof power supply, flow rate, temp. and pressure of gas; determination ofrate constants for main reactions;; monitoring of concns. of oxides and O3 by mass spectroscopy;; Kinetics;

upstream raw materials:

Nitrogen dioxide

ozone

sulfuric acid

water

Downstream raw materials:

nitric acid

nitrylfluoride

sodium nitrate

zinc(II) nitrate

Refernces

• 1、 Gagelmann, Steffen,Riess, Katja,Wickleder, Mathias S.. "Metal oxidation with N2O5: The nitrosylium nitrates (NO)Cu(NO3)3, (NO)2[Zn(NO3) 4] and (NO)6[Ni4(NO3) 12](NO3)2·(HNO3)". . p. 5160 - 5166. Retrieved 2011.
• 2、 Bencivenni,Sanna,Schriver-Mazzuoli,Schriver. "Infrared spectrum and theoretical study of the dinitrogen pentoxide molecule (N2O5) in solid argon". . p. 7836 - 7846. Retrieved 1996.
• 3、 Kane, Sean M.,Caloz, Francois,Leu, Ming-Taun. "Heterogeneous uptake of gaseous N2O5 by (NH4)2SO4, NH4HSO4, and H2SO4 aerosols". . p. 6465 - 6470. Retrieved 2001.
• 4、 Cosman,Bertram. "Reactive uptake of N2O5 on aqueous H 2so4 solutions coated with 1-component and 2-component monolayers". . p. 4625 - 4635. Retrieved 2008.
• 5、 Leu, Ming-Taun,Hatakeyama, Shiro,Hsu, Kuang-Jung. "Rate Constants for Reactions between Atmospheric Reservoir Species. 1. HCl". . p. 5778 - 5784. Retrieved 1989.
• 6、 Cosman,Knopf,Bertram. "N2O5 reactive uptake on aqueous sulfuric acid solutions coated with branched and straight-chain insoluble organic surfactants". . p. 2386 - 2396. Retrieved 2008.
• 7、 Lin, Fawei,Wang, Zhihua,Shao, Jiaming,Yuan, Dingkun,He, Yong,Zhu, Yanqun,Cen, Kefa. "Promotional effect of spherical alumina loading with manganese-based bimetallic oxides on nitric-oxide deep oxidation by ozone". . p. 1270 - 1280. Retrieved 2017.
• 8、 Vishnetskaya,Yakimova,Sidorenkova. "Superacids as catalysts of the oxidation of inorganic substrates". . p. 173 - 175. Retrieved 2006.
• 9、 Wulf, O. R.,Daniels, F.,Karrer, S.. "". . p. 2398. Retrieved 1922.
• 10、 Caba?as,Martín,Salgado,Baeza,López,Martínez. "A kinetic study of gas-phase reaction of thiophene with NO3 by using absolute and relative methods". . p. 401 - 406. Retrieved 2002.