3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

Base Information

Chemical Name:3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol
CAS No.:1428672-03-0
Molecular Formula:C₃₄H₆₂O₉Si₂
Molecular Weight:671.032
Hs Code.:

Synonyms:3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

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Chemical Property of 3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

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Technology Process of 3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

There total 5 articles about 3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1428672-02-9
11-O-[bis(4-methoxyphenyl)(phenyl)methyl]-3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

: 1428672-03-0
3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

Guidance literature:: With acetic acid; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1021/ja401918r

Reference yield:

: 1428671-98-0
(5S,6S,7R,9Z,11R)-11-{2-[bis(4-methoxyphenyl)(phenyl)methoxy]ethyl}-5-{2-[(3,4-dimethoxybenzyl)oxy]ethyl}-2,2,3,3,6,13,13,14,14-nonamethyl-4,12-dioxa-3,13-disilapentadec-9-en-7-ol

: 1428672-03-0
3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

Guidance literature:: Multi-step reaction with 5 steps

1: 20 °C

2: toluene / 3 h / 0 °C

3: dihydrogen peroxide; potassium hydrogencarbonate / methanol; tetrahydrofuran

4: toluene / 2 h / 110 °C

5: acetic acid / dichloromethane / 2 h / 20 °C

With dihydrogen peroxide; potassium hydrogencarbonate; acetic acid; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1021/ja401918r

Reference yield:

: 1428672-01-8
11-O-[bis(4-methoxyphenyl)(phenyl)methyl]-3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-D-glycero-D-gluco-undecitol

: 1428672-03-0
3,9-bis-O-[tert-butyl(dimethyl)silyl]-2,4,6,8,10-pentadeoxy-1-O-(3,4-dimethoxybenzyl)-4-methyl-5,7-O-(oxomethylene)-D-glycero-D-gluco-undecitol

Guidance literature:: Multi-step reaction with 2 steps

1: toluene / 2 h / 110 °C

2: acetic acid / dichloromethane / 2 h / 20 °C

With acetic acid; In dichloromethane; toluene;
DOI:10.1021/ja401918r