METHYL PERFLUORODECANOATE

Base Information

• Chemical Name: METHYL PERFLUORODECANOATE
• CAS No.: 307-79-9
• Molecular Formula: C11H3 F19 O2
• Molecular Weight: 528.11
• Hs Code.: 29159000
• European Community (EC) Number: 670-448-5
• DSSTox Substance ID: DTXSID60369822
• Wikidata: Q82157117
• Mol file: 307-79-9.mol

Synonyms:Decanoicacid, nonadecafluoro-, methyl ester (8CI,9CI)

Chemical Property of METHYL PERFLUORODECANOATE

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 0.547mmHg at 25°C
• Refractive Index: n20/D 1.308(lit.)
• Boiling Point: 190.2 ºCat 760 mmHg
• Flash Point: 67.3ºC
• PSA: 26.30000
• Density: 1.663 g/cm³
• LogP: 5.80410
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 9
• Exact Mass: 527.9829644
• Heavy Atom Count: 32
• Complexity: 717

Purity/Quality:

98%,99%, ^*data from raw suppliers

MethylPerfluorodecanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,F
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of METHYL PERFLUORODECANOATE

There total 3 articles about METHYL PERFLUORODECANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + perfluorodecanoic chloride (307-38-0) → perfluorodecanoic acid methyl ester (307-79-9)

Guidance literature:

With pyridine; at 0 - 5 ℃; for 4h;

DOI:10.1016/S0022-1139(00)85181-7

Reference yield:

1-decanoic acid (334-48-5) → perfluorodecanoic acid methyl ester (307-79-9)

Guidance literature:

With hydrogen fluoride; bei der anodischen Fluorierung an Nickel-Anoden und Behandlung der Reaktionsloesung mit warmem Methanol;

Reference yield:

perfluorodecanoic acid (335-76-2) → perfluorodecanoic acid methyl ester (307-79-9)

Guidance literature:

Multi-step reaction with 2 steps

1: SOCl₂, pyridine / 2 h / Heating

2: pyridine / 4 h / 0 - 5 °C

With pyridine; thionyl chloride;

DOI:10.1016/S0022-1139(00)85181-7

upstream raw materials:

1-decanoic acid

methanol

perfluorodecanoic chloride

perfluorodecanoic acid

Downstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-1-decanol

perfluorodecanamide

Refernces