Boron trifluoride tetrahydrofuran complex

Base Information

• Chemical Name: Boron trifluoride tetrahydrofuran complex
• CAS No.: 462-34-0
• Molecular Formula: C4H8BF3O
• Molecular Weight: 139.913
• Hs Code.: 29321900
• Mol file: 462-34-0.mol

Synonyms:Furan,tetrahydro-, compd. with BF3 (1:1) (7CI);Furan, tetrahydro-, compd. with BF3(6CI);Furan, tetrahydro-, compd. with boron fluoride (BF3) (1:1) (8CI);Furan,tetrahydro-, compd. with trifluoroborane (1:1);Borane, trifluoro-, compd. withtetrahydrofuran (1:1);Boron fluoride (BF3), compd. with tetrahydrofuran (1:1)(8CI);Boron fluoride, compd. with tetrahydrofuran;Boron trifluoride-THFcomplex (1:1);Boron trifluoride-tetrahydrofuran complex (1:1);Borontrifluoride-tetrahydrofuran compound;Trifluoro(tetrahydrofuran)boron;

Chemical Property of Boron trifluoride tetrahydrofuran complex

Chemical Property:

• Appearance/Colour: Colorless to light yellow liquid
• Vapor Pressure: 11Pa
• Melting Point: 12 °C
• Boiling Point: 68.3 °C at 760 mmHg
• Flash Point: 92 °C
• PSA: 17.07000
• Density: 1.268 g/cm³
• LogP: 1.67660
• Storage Temp.: Store below +30°C.
• Sensitive.: Moisture Sensitive
• Solubility.: Miscible with dimethyl formamide.
• Water Solubility.: hydrolysis

Purity/Quality:

99% ^*data from raw suppliers

Trifluoro(tetrahydrofuran)boron ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C, T
• Hazard Codes: C,T
• Statements: 34-48/23-35-20/22
• Safety Statements: 26-27-36/37/39-45-28A-23-28

MSDS Files:

Useful:

• Uses: Reactant or reagent involved in:Deoxofluorination of alcohols and carbonylsSynthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytesHydroboration-oxidation of divinylferroceneReagent involved in the synthesis of biologically active molecules such as: NK1 receptor antagonists Complex polyketide natural productsSelective serotonin reuptake inhibitors

Technology Process of Boron trifluoride tetrahydrofuran complex

There total 1 articles about Boron trifluoride tetrahydrofuran complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + boron trifluoride (7637-07-2) → boron trifluoride-tetrahydrofuran complex (462-34-0)

Guidance literature:

In Petroleum ether;

Reference yield: 95.0%

boron trifluoride-tetrahydrofuran complex (462-34-0) + Mes2P-C{=C(H)-Ph}-AltBu2 (1308317-96-5,1308318-08-2) → C34H46AlBF3P

Guidance literature:

In toluene; at 20 ℃; for 15h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic5009126

Reference yield: 93.0%

boron trifluoride-tetrahydrofuran complex (462-34-0) + sulfur tetrafluoride (7783-60-0) + N-(trimethylsilyl)phenyl(methyl)amine (17890-34-5) → N-methyl-N-phenylaminodifluorosulfiniumtetrafluoroborate

Guidance literature:

sulfur tetrafluoride; N-(trimethylsilyl)phenyl(methyl)amine; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

boron trifluoride-tetrahydrofuran complex; In dichloromethane; at 20 - 25 ℃; for 2.16667h; Inert atmosphere;

upstream raw materials:

tetrahydrofuran

boron trifluoride

Downstream raw materials:

borane pyridine

triethylamine-borane

6-chloropyridine-3-ol

3-nitrophenyldiazonium tetrafluoroborate

Refernces