17890-34-5

Basic information

• Product Name: Silanamine, N,1,1,1-tetramethyl-N-phenyl-
• Synonyms: Silanamine,N,1,1,1-tetramethyl-N-phenyl;N-methyl-N-trimethylsilyl aniline;N-trimethylsilyl-N-methylaniline;N-methyl-trimethylsilylaniline
• CAS NO: 17890-34-5
• Molecular Formula: C10H17NSi
• Molecular Weight: 179.337
• Mol File: 17890-34-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 110-112 °C(Press: 53 Torr)
• Density: 0.914±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Silanamine, N,1,1,1-tetramethyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N,1,1,1-tetramethyl-N-phenyl-(17890-34-5)
• EPA Substance Registry System: Silanamine, N,1,1,1-tetramethyl-N-phenyl-(17890-34-5)

Safety Data

• Hazardous Substances Data: 17890-34-5(Hazardous Substances Data)

Upstream product

• 25561-30-2 N,O-Bis(trimethylsilyl)trifluoroacetamide 
• 100-61-8 N-methylaniline 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 136490-81-8 S-trimethylsilyl O-i-propyldithiocarbonate 
• 100244-42-6 O-isopropyl N-methyl-N-phenylthiocarbamate 
• 55251-46-2 N-(4-methoxyphenyl)-N-methylaniline 
• 38158-65-5 N,4-dimethyl-N-phenylaniline 
• 263917-74-4 (2-methoxyphenyl)methylphenylamine 
• 13744-88-2 N‐methyl‐N‐(4‐nitrophenyl)benzenamine 
• 51480-12-7 Bis(N-methyl-N-phenylcarbamoyl)disulfane 
• 100244-48-2 ((N-methyl-N-phenylcarbamoyl)dithio)carbonyl chloride 
• 1327166-56-2 C₁₇H₁₈N₂O₂S₂ 
• 1327166-55-1 C₁₈H₂₀N₂O₂S₂ 
• 2786-62-1 3-methyl-(3H)benzothiazolone 
• 4285-42-1 N-phenyl-N-methylcarbamoyl chloride 
• 87463-05-6 (methoxycarbonyl)(carbamoyl)disulfane 
• 100244-53-9 (N-methyl-N-phenylcarbamoyl)sulfenyl chloride 

Relevant articles and documents

Deoxofluorination reactions using N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts

The synthesis of N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts is reported, and their behavior as deoxofluorinating agent was evaluated. The deoxofluorination reactions were performed using a primary alcohol, a secondary alcohol and a ketone. Results show that subtle modification of the structure of the reagents can noticeably affect the reactivity and the selectivity in deoxofluorination reactions.

DISUBSTITUTED-AMINODIFLUOROSULFINIUM SALTS, PROCESS FOR PREPARING SAME AND METHOD OF USE AS DEOXOFLUORINATION REAGENTS

The invention relates to disubstituted-aminodifluorosulfinium salts represented by the formula (I). Processes for preparing same and methods of use as deoxofluorinating reagent is also provided.

Development of a new class of chiral phosphorus ligands: P-chirogenic diaminophosphine oxides. A unique source of enantioselection in Pd-catalyzed asymmetric construction of quaternary carbons

We have recently developed a new class of chiral phosphorus ligands: P-chirogenic diaminophosphine oxides. These pentavalent phosphorus compounds have been successfully applied to Pd-catalyzed asymmetric construction of tertiary and quaternary carbons. The actual ligand structure was the trivalent phosphorus species 17, which was generated in situ by BSA-induced P(V) to P(III) transformation of 6, the preligand. Detailed mechanistic studies, including asymmetric amplification and initial rate kinetics, revealed that complex 18 [Pd-17 (1:2) complex] was the active catalyst. The important function of the nitrogen atom on the sidearm in the ligands was also clarified. The source of enantioselection in the construction of asymmetric quaternary carbons was the secondary ligand substrate interaction mediated by N-Zn coordination.