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Tributylborane

Base Information Edit
  • Chemical Name:Tributylborane
  • CAS No.:122-56-5
  • Deprecated CAS:31259-85-5
  • Molecular Formula:C12H27B
  • Molecular Weight:182.157
  • Hs Code.:29310099
  • European Community (EC) Number:204-554-6
  • DSSTox Substance ID:DTXSID9059543
  • Nikkaji Number:J55.477D
  • Wikidata:Q72509961
  • Mol file:122-56-5.mol
Tributylborane

Synonyms:tri-n-butylborane;tributylborane

Suppliers and Price of Tributylborane
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Usbiological
  • Tributylborane
  • 1g
  • $ 305.00
  • TRC
  • Tributylborane(1.0?MinTHF)
  • 2.5g
  • $ 60.00
  • TRC
  • Tributylborane(1.0?MinTHF)
  • 1g
  • $ 45.00
  • Sigma-Aldrich
  • Tributylborane
  • 50g
  • $ 277.00
  • Sigma-Aldrich
  • Tributylborane solution 1.0M in diethyl ether
  • 100ml
  • $ 182.00
  • Sigma-Aldrich
  • Tributylborane solution 1.0 M in THF
  • 100ml
  • $ 156.00
  • Alfa Aesar
  • Tri-n-butylborane 1M soln. in THF
  • 500ml
  • $ 373.00
  • Alfa Aesar
  • Tri-n-butylborane 1M soln. in THF
  • 100ml
  • $ 140.00
  • AHH
  • Tri-n-butylboron 98%
  • 100g
  • $ 280.00
Total 14 raw suppliers
Chemical Property of Tributylborane Edit
Chemical Property:
  • Appearance/Colour:colorless to pale yellow liquid 
  • Vapor Pressure:0.3mmHg at 25°C 
  • Melting Point:-34 °C 
  • Refractive Index:1.4285 
  • Boiling Point:209 °C at 760 mmHg 
  • Flash Point:94.9 °C 
  • PSA:0.00000 
  • Density:0.732 g/cm3 
  • LogP:4.88150 
  • Storage Temp.:Flammables area 
  • Sensitive.:Air Sensitive 
  • Solubility.:Benzene, Tetrahydrofuran 
  • Water Solubility.:Not miscible or difficult to mix with water. 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:9
  • Exact Mass:182.2205810
  • Heavy Atom Count:13
  • Complexity:72.1
Purity/Quality:

99% *data from raw suppliers

Tributylborane *data from reagent suppliers

Safty Information:
  • Pictogram(s): HarmfulXn; FlammableF; Corrosive
  • Hazard Codes:F,Xn,C 
  • Statements: 17-34-40-36/37/38-20/21/22-11-22-19-37 
  • Safety Statements: 7-23-26-36/37/39-43-45-16 
MSDS Files:

SDS file from LookChem

Useful:
  • Chemical Classes:Metals -> Metalloid Compounds (Boron)
  • Canonical SMILES:B(CCCC)(CCCC)CCCC
  • Uses Petrochemical industry, organic reactions, catalyst. Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.
Technology Process of Tributylborane

There total 42 articles about Tributylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
at 100 - 140 ℃; for 5h; Product distribution / selectivity;
Guidance literature:
With n-butyllithium; In hexane; Petroleum ether; byproducts: butane, LiBr; the urea in petroleum ether was refluxed under N2 with n-BuLi in hexanefor 48 h; the solvents were removed in vac., the residue was fractional distd.; elem. anal.;
Guidance literature:
With 2,6-dibromo-4,8-dimethyl-1,3,5,7-tetraphenylbenzobis(diazaborole); In hexane; toluene; at -78 ℃; for 1h;
DOI:10.1039/c9dt03818c
Refernces Edit

Boron containing two-photon absorbing chromophores. 2. Fine tuning of the one- and two-photon photophysical properties of pyrazabole based fluorescent bioprobes

10.1021/ic900627g

The research focuses on the synthesis and photophysical characterization of new boron-containing two-photon absorbing fluorophores centered on a pyrazabole core. The study explores the fine-tuning of these fluorophores' one- and two-photon properties by modifying the central core and donor groups. Key chemicals involved in the synthesis include 4-iodopyrazole, tributylborane, 4-bromophenylboronic acid, trimethylsilylacetylene, tetrabutylammonium fluoride, and various donor groups such as alkoxy, diphenylamino, and boron dipyromethene (BODIPY) groups. The synthesized fluorophores exhibit efficient fluorescence and high two-photon absorption cross-sections, making them suitable for two-photon excited microscopy (TPEM) applications. The research also includes molecular calculations to understand the electronic structure and photophysical behavior of these compounds, highlighting their potential for bioimaging and other multiphoton applications.

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