623-76-7Relevant articles and documents
INFRARED STUDY OF THE ADSORPTION OF ETHYL ISOCYANATE ON SILICA IMMERSED IN TETRACHLORIDE
Cross, Stephen N. W.,Rochester, Colin H.
, p. 1945 - 1952 (1981)
Infrared spectra are reported of silica immersed in solutions of ethyl isocyanate in carbon tetrachloride.Interactions between surface silanol groups and ethyl isocyanate led to the formation of a surface urethane, ethylamine and 1,3-diethylurea as the products of adsorption.Increasing hydroxyl population of the silica surface enhanced the formation of 1,3-diethylurea but diminished the extent of reaction of isolated silanol groups to give urethane.Adsorbed ethylammonium ions were produced by proton transfer from silanol groups to ethylamine molecules at the solid/liquid interface.The results are discussed in relation to previous spectroscopic data for the adsorption of ethyl isocyanate on silica at the solid/vapour interface.
CARBONATE DERIVATIVE PRODUCTION METHOD
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Paragraph 0153-0154; 0161-0162, (2020/04/09)
The objective of the present invention is to provide a method for producing a carbonate derivative in a safe and efficient manner. The method for producing a carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a C1-4 halogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a nucleophilic functional group-containing compound and the specific base in the presence of oxygen.
Synthesis, thermolysis, photolysis and antimicrobial evaluation of some novel semicarbazones and thiosemicarbazones derived from 3-methyl-2-benzothiazolinone hydrazone
Yosef, Hisham Abdallah A.,Ibrahim, Nabila M.
, p. 867 - 886 (2017/04/17)
REACTION of 3-methyl-2-benzothiazolinone hydrazone (1) with?? some selected isocyanate and isothiocyanate reagents 2a-j gave the respective semicarbazones and thiosemicarbazones 3a-j. Thermolysis of compound 3a under reduced pressure gave N,N'-diethylurea (4) in addition to 1,2-bis(3-methylbenzo[d]thiazol-2(3H)-ylidene)hydrazine (5). Compound 3a was almost quantitatively recovered upon its exposure to sunlight in methanol for 60 days. Elementary and spectroscopic measurements (IR, 1H NMR, 13C NMR, MS) are in good accord with the structures postulated for the new compounds. The single crystal X-ray crystallographic analysis of 3f was given and its data were discussed. The synthesized compounds 3aj as well as the hydrazone 1 were screened for their antibacterial properties against Bacillus subtilis (G+), Escherichia coli (G-), Pseudomonas aeruginosa (G-) and Staphylococcus aureus (G+) and for their antifungal properties against Aspergillus flavus and Candida albicans. Some of the tested compounds showed an activity against the four bacterial strains where their order of activity was found to be 1 > 3g > 3j > 3i > 3e > 3h > 3a. The MIC90 value of compound 1 against P. aeruginosa was 9 mg/ml. On the other hand only compound 1 showed a significant activity against A. flavus fungal species where it recorded an inhibition zone diameter value (16 mm/mg) which is very near to that of the standard drug, amphotericin B (17 mm/mg). However, the C. albicans was found to be insensitive to all of the investigated compounds.
Microwave-assisted synthesis of symmetrical and unsymmetrical N,N 0-disubstituted thioureas and ureas over MgO in dry media
Valizadeh, Hassan,Dinparast, Leila
experimental part, p. 251 - 254 (2012/07/01)
Under mild microwave irradiation conditions a variety of symmetrical and unsymmetrical A,N′-disubsti-tuted thioureas and ureas were prepared via the reaction of Af-monosubstituted hydroxylamines with isocyanate and isothiocyanate derivatives over MgO under solvent-free conditions. This new method afforded satisfactory results with good yields, short reaction time, and simplicity in the experimental procedure.