cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)

Base Information

• Chemical Name: cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)
• CAS No.: 81616-41-3
• Molecular Formula: C₃₉H₄₈O₃P₄Ru
• Molecular Weight: 789.773
• Mol file: 81616-41-3.mol

Synonyms:cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)

Chemical Property of cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)

There total 1 articles about cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

RuHBH4(C6H5P(CH2CH2CH2P(C6H5)2)2) (81624-51-3) + phosphorous acid trimethyl ester (121-45-9) → cis-RuH2(P(OMe3)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine) (81616-41-3)

Guidance literature:

With NEt₃; In tetrahydrofuran; to soln. of Ru-complex in THF were added P(OMe)3 and NEt3, stirred for 2 h at 25°C under N2; vol. was reduced, hexane was added, allowed to stand overnight, filtered, washed with hexane, dried in vac.; elem. anal.;

DOI:10.1021/ja00378a019

Reference yield: 86.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + cis-RuH2(P(OMe3)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine) (81616-41-3) + acetonitrile (75-05-8,26809-02-9) → {RuH(CH3CN)(P(OCH3)3)(C6H5P((CH2)3P(C6H5)2)2)}(1+)*BF4(1-)={RuH(CH3CN)(P(OCH3)3)(C6H5P((CH2)3P(C6H5)2)2)}BF4 (84623-68-7)

Guidance literature:

In tetrahydrofuran; CH3CN added to complex soln., 1 equiv of HBF4*(C2H5)2O added; solid pptd. during a 2-h period, isolated, washed with THF and hexane, dried (vac.);

DOI:10.1021/om00078a001

Reference yield: 85.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + cis-RuH2(P(OMe3)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine) (81616-41-3) → {RuH(CO)(P(OMe3)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF4 (84623-62-1)

Guidance literature:

With CO; In tetrahydrofuran; CO bubbled through a soln. of the Ru complex; addn. of 1 equiv of HBF4*(C2H5)2O; after 30 min, N2 is bubbled through the mixt. for 10 min; solid isolated, washed with Et2O, dried (vac.); elem. anal.;

DOI:10.1021/om00078a001

upstream raw materials:

RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

phosphorous acid trimethyl ester

Downstream raw materials:

trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

{RuH(CO)(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

{RuH(CH₃CN)(P(OCH₃)3)(C₆H₅P((CH₂)3P(C₆H₅)2)2)}⁽¹⁺⁾*BF₄^(1-)={RuH(CH₃CN)(P(OCH₃)3)(C₆H₅P((CH₂)3P(C₆H₅)2)2)}BF₄