Benzenepropanal, 3-(1,1-diMethylethyl)-

Base Information

• Chemical Name: Benzenepropanal, 3-(1,1-diMethylethyl)-
• CAS No.: 1023288-21-2
• Molecular Formula: C₁₃H₁₈O
• Molecular Weight: 190.285
• Mol file: 1023288-21-2.mol

Synonyms:m-t-butylphenyl propionaldehyde

Chemical Property of Benzenepropanal, 3-(1,1-diMethylethyl)-

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

3-(3'-Tert-butylphenyl)propionaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenepropanal, 3-(1,1-diMethylethyl)-

There total 3 articles about Benzenepropanal, 3-(1,1-diMethylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-(tert-butyl)-3-iodobenzene (58164-02-6) + allyl alcohol (107-18-6) → m-t-butylphenyl propionaldehyde (1023288-21-2)

Guidance literature:

With tetrabutyl-ammonium chloride; palladium diacetate; sodium hydrogencarbonate; In N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1016/j.bmcl.2009.05.119

Reference yield: 63.0%

carbon monoxide (201230-82-2) + 1-(tert-butyl)-3-vinylbenzene (19789-36-7) → m-t-butylphenyl propionaldehyde (1023288-21-2)

Guidance literature:

With triphenyl phosphite; hydrogen; Rh(acac)(CO)2; In toluene; at 80 ℃; for 6h; under 750.075 Torr;

Reference yield:

4-tert-butyltoluene (98-51-1) + acetaldehyde (75-07-0,9002-91-9) → m-t-butylphenyl propionaldehyde (1023288-21-2) + 3-(4-tert-butylphenyl)propionaldehyde (18127-01-0)

Guidance literature:

4-tert-butyltoluene; With iron(III) chloride; In toluene; at 20 ℃; for 0.5h;

acetaldehyde; zinc(II) oxide; at 130 - 180 ℃; for 1.5h; Autoclave;

With hydrogen; palladium-on-charcoal; In ethanol; at 50 ℃; under 15001.5 Torr; Product distribution / selectivity; Autoclave;

upstream raw materials:

carbon monoxide

1-(tert-butyl)-3-vinylbenzene

1-(tert-butyl)-3-iodobenzene

allyl alcohol

Downstream raw materials:

2-[2-(3-tert-butylphenyl)ethyl]-1,3-dioxolane

C₁₄H₁₈N₂S