(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

Base Information

Chemical Name:(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane
CAS No.:1404195-49-8
Molecular Formula:C₂₂H₄₂O₂Si₂
Molecular Weight:394.745
Hs Code.:

Synonyms:(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

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Technology Process of (S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

There total 1 articles about (S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 1404195-48-7
(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

: 1404195-49-8
(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

Guidance literature:: (R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone; With iron(III) chloride; methylmagnesium bromide; In tetrahydrofuran; at 0 ℃; for 2h; Inert atmosphere;

chloro-trimethyl-silane; With triethylamine; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; for 15h; Inert atmosphere;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k

Reference yield:

: 1404195-49-8
(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

: 1404195-50-1
(2S,5S)-2-hydroxy-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-3-enone

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 2h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k

Reference yield:

: 1404195-49-8
(S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane

: 1404195-53-4
C₁₉H₃₄O₃Si

: 1404195-64-7
(R)-4-hydroxy-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Guidance literature:: (S)-triisopropyl(2-(4-methyl-5-(trimethylsilyloxy)cyclohexa-2,4-dienyl)allyloxy)silane; With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane; at -78 ℃; for 1h; Irradiation;

With thiourea; In dichloromethane; Overall yield = 26 %; Overall yield = 9 mg;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k