(S,S)-(+)-1,2-CYCLODODECANEDIOL

Base Information

• Chemical Name: (S,S)-(+)-1,2-CYCLODODECANEDIOL
• CAS No.: 118101-31-8
• Molecular Formula: C12H24 O2
• Molecular Weight: 200.321
• Mol file: 118101-31-8.mol

Synonyms:(S,S)-(+)-1,2-CYCLODODECANEDIOL

Chemical Property of (S,S)-(+)-1,2-CYCLODODECANEDIOL

Chemical Property:

• PSA: 40.46000
• LogP: 2.62280

Purity/Quality:

99% ^*data from raw suppliers

(S,S)-(+)-1,2-CYCLODODECANEDIOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (S,S)-(+)-1,2-CYCLODODECANEDIOL

There total 5 articles about (S,S)-(+)-1,2-CYCLODODECANEDIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

cyclododecene (1501-82-2) → (1S,2S)-Cyclododecane-1,2-diol (118101-31-8) + 1,2-epoxycyclododecane (286-99-7)

Guidance literature:

With H₅PV₂Mo₁₀O₄₀; oxygen; sodium sulfite; In acetic acid; at 65 - 110 ℃; for 4h; under 750.075 Torr;

DOI:10.1039/c4cc06304j

Reference yield:

dodecanedial (38279-34-4) → cis-1,2-cyclododecanediol (4422-05-3) + cis-1,2-cyclododecanediol (4422-05-3,5202-26-6,15199-41-4,118101-28-3,118101-30-7,118101-31-8)

Guidance literature:

With TiCl₃(DME)2; copper; zinc; In 1,2-dimethoxyethane; at 25 ℃; for 38h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)72707-9

Reference yield:

→ cis-1,2-cyclododecanediol (4422-05-3,5202-26-6,15199-41-4,118101-28-3,118101-30-7,118101-31-8)

Guidance literature:

With pyridine; osmium(VIII) oxide;

DOI:10.1002/hlca.19550380715

upstream raw materials:

dodecanedial

formic acid

cis-cyclododecene

dihydrogen peroxide

Downstream raw materials:

1,12-dodecanedioic acid

dodecanedial

Refernces

• 1、 McMurry, John E.,Rico, Joseph G.. "SYNTHESIS OF 1,2-CYCLOALKANEDIOLS BY INTRAMOLECULAR TITANIUM-INDUCED PINACOL COUPLING". . p. 1169 - 1172. Retrieved 2007/10/02.