{(tetraphenylporphinato)Rh(dimethylamine)2}Cl

Base Information

• Chemical Name: {(tetraphenylporphinato)Rh(dimethylamine)2}Cl
• CAS No.: 51669-90-0
• Molecular Formula: C₄₈H₄₂N₆Rh*Cl
• Molecular Weight: 841.26
• Mol file: 51669-90-0.mol

Synonyms:{(tetraphenylporphinato)Rh(dimethylamine)2}Cl

Chemical Property of {(tetraphenylporphinato)Rh(dimethylamine)2}Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(tetraphenylporphinato)Rh(dimethylamine)2}Cl

There total 1 articles about {(tetraphenylporphinato)Rh(dimethylamine)2}Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + rhodium(III) chloride trihydrate + N,N-dimethyl-formamide (68-12-2,33513-42-7) → {(tetraphenylporphinato)Rh(dimethylamine)2}Cl (51669-90-0) + (dimethylamine)(chlorotetraphenylporphinato)rhodium(III) (99147-88-3)

Guidance literature:

In N,N-dimethyl-formamide; refluxing Rh(III)chloride (3.23mmol) in DMF (50ml) for 0.5 h; addn. of a suspension of porphyrine (0.81mmol) in DMF (500ml) to the soln.; refluxing for 24 h; cooling to room temp.;; pouring into water; extn. by CH2Cl2; concn., passing through an aluminacolumn, second CH2Cl2 fraction: mono N(CH3)2H complex (recrystn. from CH2Cl2/n-hexane), elution with CH2Cl2/CH3OH (100:1): bis adduct (recrystn. from CH2Cl2/n-hexane/CH3OH);;

Reference yield: 90.0%

silver(I) hexafluorophosphate (26042-63-7) + {(tetraphenylporphinato)Rh(dimethylamine)2}Cl (51669-90-0) → [Rh(C44H28N4)(NH(CH3)2)2](1+)*PF6(1-)=[Rh(C44H28N4)(NH(CH3)2)2]PF6 (106150-38-3)

Guidance literature:

In acetone; suspending of 300 mg of (Rh(C44H28N4)(NH(CH3)2)2)Cl in acetone with thestoichiometric amount of AgPF6; stirring for 24 h under N2; evaporationof solvent;; chromy. (silica gel, THF); evaporation of the eluted fractions or recrystallization from THF/hexane; elem. anal.;;

DOI:10.1016/S0020-1693(00)84339-X

Reference yield:

{(tetraphenylporphinato)Rh(dimethylamine)2}Cl (51669-90-0) → Rh(meso-tetraphenylporphynato)(CH2Cl)

Guidance literature:

With dichloromethane; In dichloromethane; Electrochem. Process; soln. of Rh complex (0.2 M TBAP) electrolyzed at -1.30 V, 30 min, room temp., evapn. to dryness, Schlenk technique; purifn. by extn. with acetonitrile (4x);

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

N,N-dimethyl-formamide

Downstream raw materials:

{(tetraphenylporphinato)Rh(n-pentyl)}

{(tetraphenylporphinato)Rh(n-propyl)}

{(tetraphenylporphinato)Rh(n-hexyl)}

[Rh(C₄₄H₂₈N₄)(NH(CH₃)2)2]⁽¹⁺⁾*PF₆^(1-)=[Rh(C₄₄H₂₈N₄)(NH(CH₃)2)2]PF₆