(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

Base Information

Chemical Name:(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal
CAS No.:470470-64-5
Molecular Formula:C₂₀H₃₄O₃Si
Molecular Weight:350.574
Hs Code.:

Synonyms:(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

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Chemical Property of (S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

Chemical Property:

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Technology Process of (S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

There total 10 articles about (S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 470470-63-4
(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentan-1-ol

: 470470-64-5
(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 ℃; for 0.333333h;
DOI:10.1016/S0040-4039(02)01054-7

Reference yield:

: 147252-93-5
(3S)-3-(benzyloxy)-2,2-dimethyl-4-penten-1-ol

: 470470-64-5
(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: 91 percent / imidazoline; DMAP

2.1: BH₃*THF / 3 h

2.2: 72 percent / aq. H₂O₂; NaOH

3.1: (COCl)2; DMSO; Et₃N

With 2-imidazoline; dmap; borane-THF; oxalyl dichloride; dimethyl sulfoxide; triethylamine;
DOI:10.1016/j.tetlet.2004.09.124

Reference yield:

: 470470-82-7
((S)-3-benzyloxy-2,2-dimethyl-pent-4-enyloxy)-tert-butyl-dimethyl-silane

: 470470-64-5
(S)-3-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentanal

Guidance literature:: Multi-step reaction with 2 steps

1.1: BH₃*THF / 3 h

1.2: 72 percent / aq. H₂O₂; NaOH

2.1: (COCl)2; DMSO; Et₃N

With borane-THF; oxalyl dichloride; dimethyl sulfoxide; triethylamine;
DOI:10.1016/j.tetlet.2004.09.124