{Et4N}2{W2(CO)8(μ-SPh)2}

Base Information

Chemical Name:{Et4N}2{W2(CO)8(μ-SPh)2}
CAS No.:97092-71-2
Molecular Formula:2C₈H₂₀N*C₂₀H₁₀O₈S₂W₂
Molecular Weight:1070.63
Hs Code.:

Synonyms:{Et4N}2{W2(CO)8(μ-SPh)2}

Suppliers and Price of {Et4N}2{W2(CO)8(μ-SPh)2}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {Et4N}2{W2(CO)8(μ-SPh)2}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {Et4N}2{W2(CO)8(μ-SPh)2}

There total 3 articles about {Et4N}2{W2(CO)8(μ-SPh)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 14040-11-0
tungsten hexacarbonyl

: 56-34-8
tetraethylammonium chloride

: 930-69-8
sodium thiophenolate

: 97092-71-2
{Et4N}2{W2(CO)8(μ-SPh)2}

Guidance literature:: In acetonitrile; byproducts: NaCl, CO; under inert atmosphere, a soln. of (Et4N)(SPh) was generated by react. of equimolar amts. of NaSPh and anhyd. (Et4N)Cl at 50°C for 1.5 h, the slurry was filtered (to remove NaCl) onto solid W(CO)6 (1 equiv.), stirred under reflux for 5 h, cooled; filtered, evapd. under vac., i-PrOH was added, filtered, washed (i-PrOH), dried in vac.; elem. anal.;

Reference yield:

: 116148-13-1
{(C₂H₅)4N}⁽¹⁺⁾*{W(CO)5(S(C₆H₅))}^(1-) = {(C₂H₅)4N}{W(CO)5(S(C₆H₅))}

: 97092-71-2
{Et4N}2{W2(CO)8(μ-SPh)2}

Guidance literature:: With CS₂; In tetrahydrofuran; N2 atmosphere; 4 d; IR monitoring;

Reference yield:

: 14040-11-0
tungsten hexacarbonyl

: 3193-72-4
tetraethylammonium phenylthiolate

: 97092-71-2
{Et4N}2{W2(CO)8(μ-SPh)2}

Guidance literature:: In acetonitrile; W(CO)6 was reacted with ligand in refluxing (ca 80°C) MeCN for 5h; filtered, filtrate was concd., i-PrOH was added; elem. anal.;
DOI:10.1016/S0020-1693(00)87947-5