[4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane

Base Information

• Chemical Name: [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane
• CAS No.: 881917-50-6
• Molecular Formula: C₃₁H₁₅Cl₈N
• Molecular Weight: 685.091
• Mol file: 881917-50-6.mol

Synonyms:[4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane

Chemical Property of [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane

There total 9 articles about [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + tris(2,4,6‐trichlorophenyl)methyl radical (109745-46-2) → [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane (881917-50-6)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 160 ℃; for 2.16667h; Inert atmosphere; Darkness;

DOI:10.1002/anie.201500242

Reference yield: 39.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + tris(2,4,6‐trichlorophenyl)methyl radical (109745-46-2) → [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane (881917-50-6) + bis[4-(N-carbazolyl)-2,6-dichlorophenyl](2,4,6-trichlorophenyl)methane (1018803-41-2) + tris[4-(N-carbazolyl)-2,6-dichlorophenyl]methane (1018803-45-6) + tris(2,4,6-trichlorophenyl)methane (105633-27-0)

Guidance literature:

9H-carbazole; tris(2,4,6‐trichlorophenyl)methyl radical; With caesium carbonate; In N,N-dimethyl-formamide; for 2h; Heating;

With hydrogenchloride; In N,N-dimethyl-formamide; Further stages.;

DOI:10.1021/jo702723k

Reference yield: 33.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + tris(2,4,6‐trichlorophenyl)methyl radical (109745-46-2) → [4-(N-carbazolyl)-2,6-dichlorophenyl]bis(2,4,6-trichlorophenyl)methane (881917-50-6) + (4-(N-carbazolyl)-2,6-dichlorophenyl)bis(2,4,6-trichlorophenyl)methyl radical (881917-48-2)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; for 1h; Heating;

DOI:10.1016/j.tetlet.2006.02.022

upstream raw materials:

(4-(N-carbazolyl)-2,6-dichlorophenyl)bis(2,4,6-trichlorophenyl)methyl radical

9H-carbazole

tris(2,4,6‐trichlorophenyl)methyl radical

1,3,5-trichlorobenzene

Downstream raw materials:

[2,6-dichloro-4-(3,6-dibromo-N-carbazolyl)phenyl]bis(2,4,6-trichlorophenyl)methane

[2,6-dichloro-4-(3,6-dichloro-N-carbazolyl)phenyl]bis(2,4,6-trichlorophenyl)methane

[2,6-dichloro-4-(3,6-diacetyl-N-carbazolyl)phenyl]bis(2,4,6-trichlorophenyl)methane

[2,6-dichloro-4-(3,6-diethyl-N-carbazolyl)phenyl]bis(2,4,6-trichlorophenyl)methane