Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide

Base Information

• Chemical Name: Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide
• CAS No.: 108200-50-6
• Molecular Formula: C₁₀H₉F₃O₂S
• Molecular Weight: 250.241
• Mol file: 108200-50-6.mol

Synonyms:Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide

Chemical Property of Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide

There total 4 articles about Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2,2,2-trifluoroethyl phenyl sulfide (2262-07-9) + acetic acid (64-19-7,77671-22-8) → Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide (108200-50-6)

Guidance literature:

With 2-(morpholin-4-yl)ethyl modified polystyrene; In acetonitrile; Electrochemical reaction;

DOI:10.1002/anie.200500977

Reference yield: 53.0%

2,2,2-trifluoroethyl phenyl sulfide (2262-07-9) + potassium acetate (127-08-2) → Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide (108200-50-6)

Guidance literature:

In acetic acid; Ambient temperature; platinum plates (3*2 cm) as anode and cathode; constant current 1.2 A/dm²; 4 F/mol;

DOI:10.1016/S0040-4020(01)87052-6

Reference yield: 42.0%

2,2,2-trifluoroethyl phenyl sulfoxide (79695-52-6) + acetylacetone (123-54-6,81235-32-7) → Phenyl 1-acetoxy-2,2,2-trifluoroethyl sulfide (108200-50-6)

Guidance literature:

at 120 ℃; for 24h;

DOI:10.1016/S0040-4039(00)83902-7

upstream raw materials:

2,2,2-trifluoroethyl phenyl sulfide

potassium acetate

acetic acid

2,2,2-trifluoroethyl phenyl sulfoxide

Downstream raw materials:

phenylhydrazone of trifluoroacetaldehyde