79695-52-6Relevant academic research and scientific papers
SYNTHETIC UTILITY OF A FLUORINE-FACILITATED CLAISEN REARRANGEMENT: A NOVEL SYNTHETIC METHOD FOR 2,4-ALKANEDIENOIC ACIDS USING 2,2,2-TRIFLUOROETHYL PHENYL SULFOXIDE
Nakai, Takeshi,Tanaka, Kiyoshi,Ogasawara, Kyo,Ishikawa, Nobuo
, p. 1289 - 1292 (1981)
A novel synthetic method for 2,4-alkadienoic acids from allylic alcohols and 2,2,2-trifluoroethyl phenyl sulfoxide is described which involves the in situ Claisen rearrangement facilitated by the fluorine.This method was applied to the stereocontrolled synthesis of pellitorine, a natural insecticide.
Electrolytic Reactions of Fluoro Organic Compounds. 7. Anodic Methoxylation and Acetoxylation of 2,2,2-Trifluoroethyl Sulfides. Preparation of Highly Useful Trifluoromethylated Building Blocks
Fuchigami, Toshio,Yamamoto, Kayoko,Nakagawa, Yuki
, p. 137 - 142 (2007/10/02)
Anodic methoxylation and acetoxylation of 2,2,2-trifluoroethyl sulfides and the corresponding nonfluorinated sulfides were comparatively studied.It was found that a trifluoromethyl group remarkably promoted anodic substitution and methoxy and acetoxy groups were introduced adjacent to the trifluoromethyl group of the sulfides.Longer perfluoroalkyl groups also promoted these anodic substitutions.These products were shown to be highly useful building blocks fro the synthesis of fluoro organic compounds.
ELECTROLYTIC TRANSFORMATION OF FUNCTIONAL GROUPS OF FLUOROORGANIC COMPOUNDS. I. ANODIC METHOXYLATION AND ACETOXYLATION OF TRIFLUOROETHYL SULFIDE
Fuchigami, Toshio,Nakagawa, Yuuki,Nonaka Tsutomu
, p. 3869 - 3872 (2007/10/02)
Anodic methoxylation and acetoxylation of phenyl trifluoroethyl sulfide were successfully performed to give the corresponding α-methoxy and α-acetoxy sulfides in good to excellent yields, respectively.These products were found to be useful building blocks
