N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

Base Information

Chemical Name:N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide
CAS No.:1443038-12-7
Molecular Formula:C₃₀H₁₈Cl₂F₄N₂O₆
Molecular Weight:649.382
Hs Code.:

Synonyms:N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

Chemical Property:

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Technology Process of N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

There total 7 articles about N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1443038-02-5
[4-(4-fluorobenzoyl)-2-chloro-6-fluorophenoxy]ethanoic acid

: 1443038-07-0
[2-chloro-6-fluoro-4-(4-fluoro-benzoyl)-phenoxy]acetic acid hydrazide

: 1443038-12-7
N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

Guidance literature:: With 2,6-dimethylpyridine; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1016/j.ejmech.2013.02.040

Reference yield:

: 1443037-87-3
2-chloro-6-fluorophenyl-4-fluorobenzoate

: 1443038-12-7
N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

Guidance literature:: Multi-step reaction with 4 steps

1: aluminum (III) chloride / 1 h / 150 °C

2: potassium carbonate / N,N-dimethyl-formamide / 3 h / 60 °C

3: sodium hydroxide; water / tetrahydrofuran / 1 h / 20 °C

4: 2,6-dimethylpyridine; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate / dichloromethane / 12 h / 20 °C

With 2,6-dimethylpyridine; aluminum (III) chloride; water; potassium carbonate; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; sodium hydroxide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 1: |Fries Phenol Ester Rearrangement;
DOI:10.1016/j.ejmech.2013.02.040

Reference yield:

: 2040-90-6
2-chloro-6-fluorophenol

: 1443038-12-7
N,N-di[di(2-chloro-6-fluoro-4-(4-fluoro-benzoyl)phenoxy)]acetyl hydrazide

Guidance literature:: Multi-step reaction with 5 steps

1: triethylamine / dichloromethane / 3 h / 0 - 20 °C

2: aluminum (III) chloride / 1 h / 150 °C

3: potassium carbonate / N,N-dimethyl-formamide / 3 h / 60 °C

4: sodium hydroxide; water / tetrahydrofuran / 1 h / 20 °C

5: 2,6-dimethylpyridine; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate / dichloromethane / 12 h / 20 °C

With 2,6-dimethylpyridine; aluminum (III) chloride; water; potassium carbonate; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; sodium hydroxide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 2: |Fries Phenol Ester Rearrangement;
DOI:10.1016/j.ejmech.2013.02.040