N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide

Base Information

• Chemical Name: N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide
• CAS No.: 1253119-87-7
• Molecular Formula: C₄₄H₅₃N₅O₉
• Molecular Weight: 795.933
• Mol file: 1253119-87-7.mol

Synonyms:N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide

Chemical Property of N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide

There total 10 articles about N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

4-tert-butylbenzoic acid hydrazide (43100-38-5) + 3-(4-nitro-phenoxy)-benzoic acid hydrazide + 2,5-bis(hexyloxy)terephthaloxy chrloride (103761-95-1) → N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide (1253119-87-7)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 12h;

Reference yield:

4-(1,1-dimethylethyl)benzoic acid (98-73-7) → N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide (1253119-87-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: N,N-dimethyl-formamide; thionyl chloride / 8 h / 20 - 80 °C

1.2: 12 h / 65 °C

2.1: tetrahydrofuran / 12 h / 20 °C

With thionyl chloride; N,N-dimethyl-formamide; In tetrahydrofuran;

Reference yield:

4-Fluoronitrobenzene (350-46-9,178603-76-4) → N'-1-(4-t-butylbenzoyl)-2,5-bis(hexyloxy)-N'-4-(3-(4-nitrophenoxy)benzoyl)terephthalohydrazide (1253119-87-7)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate / dimethyl sulfoxide / 12 h / 130 °C

2: hydrogenchloride / water / 12 h / 110 °C

3: hydrazine hydrate / ethanol / 24 h / Reflux

4: tetrahydrofuran / 12 h / 20 °C

With hydrogenchloride; potassium carbonate; hydrazine hydrate; In tetrahydrofuran; ethanol; water; dimethyl sulfoxide;

upstream raw materials:

4-(1,1-dimethylethyl)benzoic acid

3-Carboxyphenol

4-Fluoronitrobenzene

1-bromo-hexane

Downstream raw materials:

2-(2,5-bis(hexyloxy)-4-(5-(3-(4-nitrophenoxy)phenyl)-1,3,4-oxadiazole-2-yl)phenyl)-5-(4-t-butylphenyl)-1,3,4-oxadiazole

2-(5-(4-t-butylphenyl)-1,3,4-oxadiazole-2-yl)-5-(5-(3-(4-nitrophenoxy)phenyl)-1,3,4-oxadiazole-2-yl)benzene-1,4-diol

2-(5-(3-(4-aminophenoxy)phenyl)-1,3,4-oxadiazole-2-yl)-5-(5-(4-t-butylphenyl)-1,3,4-oxadiazole-2-yl)benzene-1,4-diol

2-(5-(4-t-butylphenyl)-1,3,4-oxadiazole-2-yl)-5-(5-(3-(4-(2-(2-hydroxyphenyl)-4,5-diphenyl-1H-imidazole-1-yl)phenoxy)phenyl)-1,3,4-oxadiazole-2-yl)benzene-1,4-diol