Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄

Base Information

• Chemical Name: Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄
• CAS No.: 155311-39-0
• Molecular Formula: BF₄*C₄₂H₄₂IrN₂OP₂
• Molecular Weight: 931.78
• Mol file: 155311-39-0.mol

Synonyms:Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄

Chemical Property of Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄

There total 1 articles about Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH)⁽¹⁺⁾*BF₄^(1-)=(Ir(H)2(P(C₆H₅)3)2(OC(CH₃)2)(C₃H₃NNH))BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

NH-pyrazole (288-13-1) + [Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4) (82582-67-0,72414-17-6) → Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH)(1+)*BF4(1-)=(Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH))BF4 (155311-39-0)

Guidance literature:

In acetone; byproducts: acetone; to a soln. of Ir-compd. stoichiometric amt. of pyrazole is added (Ar); after concentration diethyl ether is added, ppt. is washed with diethyl ether, elem. anal.;

DOI:10.1016/0022-328X(94)88052-2

Reference yield: 90.0%

Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH)(1+)*BF4(1-)=(Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH))BF4 (155311-39-0) + phosphorous acid trimethyl ester (121-45-9) → {IrH2(P(OCH3)3)(C3H3N2H)(P(C6H5)3)2}(1+)*BF4(1-)={IrH2(P(OCH3)3)(C3H3N2H)(P(C6H5)3)2}{BF4} (155311-43-6)

Guidance literature:

In tetrahydrofuran; under Ar, treating a suspn. of Ir-complex with a slight excess of trimethyl phosphite, stirring for 5 h at room temperature; concg., addn. of hexane, filtn., washing (hexane), drying (vac.), elem. anal.;

DOI:10.1016/0022-328X(94)88020-4

Reference yield: 88.0%

Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH)(1+)*BF4(1-)=(Ir(H)2(P(C6H5)3)2(OC(CH3)2)(C3H3NNH))BF4 (155311-39-0) → {IrH2(NCCH3)(C3H3N2H)(P(C6H5)3)2}(1+)*BF4(1-)={IrH2(CH3CN)(C3H3N2H)(P(C6H5)3)2}{BF4} (155311-45-8,155418-13-6)

Guidance literature:

With acetonitrile; In acetonitrile; byproducts: (CH3)2CO; under Ar, stirring a soln. of Ir-complex for 1 h at room temperature; concg. (vac.), addn. of Et2O, filtn., washing (Et2O), drying (vac.), elem. anal., ratio of cis- to trans-isomer = 95 : 5;

DOI:10.1016/0022-328X(94)88020-4

upstream raw materials:

NH-pyrazole

[Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4)

Downstream raw materials:

{IrH₂(P(OCH₃)3)(C₃H₃N₂H)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)={IrH₂(P(OCH₃)3)(C₃H₃N₂H)(P(C₆H₅)3)2}{BF₄}

{IrH₂(CO)(C₃H₃N₂H)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)={IrH₂(CO)(C₃H₃N₂H)(P(C₆H₅)3)2}{BF₄}

{IrH₂(NCCH₃)(C₃H₃N₂H)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)={IrH₂(CH₃CN)(C₃H₃N₂H)(P(C₆H₅)3)2}{BF₄}