p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

Base Information

Chemical Name:p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside
CAS No.:1242437-40-6
Molecular Formula:C₅₈H₆₉N₃O₁₂SSi
Molecular Weight:1060.35
Hs Code.:

p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

Synonyms:p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

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Chemical Property of p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

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Technology Process of p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

There total 1 articles about p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1242437-74-6
p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside

: 123-76-2
levulinic acid

: 1242437-40-6
p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; Inert atmosphere;
DOI:10.1002/chem.201000987

Reference yield: 94.0%

: 1242437-40-6
p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

: 86953-66-4
3-amino>-1-propanol

: 1242437-76-8
N-benzyl-N-benzyloxycarbonyl-3-aminopropyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

Guidance literature:: p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside; With silver trifluoromethanesulfonate; In diethyl ether; dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve;

With p-methylbenzenesulfenyl chloride; In diethyl ether; dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve;

3-amino>-1-propanol; In diethyl ether; dichloromethane; at -78 - -10 ℃; for 2h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/chem.201000987

Reference yield: 93.0%

: 64-17-5
ethanol

: 1242437-40-6
p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside

: 1242437-75-7
ethyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-α-L-idopyranoside

Guidance literature:: p-tolyl 2-azido-3,6-di-O-benzyl-4-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranosyl-(1->4)-2-O-benzoyl-3-O-benzyl-6-O-levulinoyl-1-thio-α-L-idopyranoside; With silver trifluoromethanesulfonate; In diethyl ether; dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve;

With p-methylbenzenesulfenyl chloride; In diethyl ether; dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere; Molecular sieve;

ethanol; In diethyl ether; dichloromethane; at -78 - -10 ℃; for 2h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/chem.201000987