(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

Base Information

Chemical Name:(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)
CAS No.:93304-78-0
Molecular Formula:C₂₆H₂₅NO₂PRe
Molecular Weight:600.671
Hs Code.:

(C<sub>5</sub>H<sub>4</sub>(C(O)CH<sub>3</sub>))Re(NO)(P(C<sub>6</sub>H<sub>5</sub>)3)(CH<sub>3</sub>)

Synonyms:(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

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Chemical Property of (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

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Technology Process of (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

There total 4 articles about (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 82582-46-5
(η5-C5H5)Re(NO)(PPh3)(COCH3)

: 93304-78-0
(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

Guidance literature:: With methyl iodide; In tetrahydrofuran; hexane; under dry N2; soln. of Re complex in THF is cooled to -78°C, slow addn. with stirring soln. of Li(N(i-Pr)2) in hexane; after 20 min addn. of CH3I, stirred for 30 min at -78°C; solvents removed under oil pump vac. at 0°C, chromd. (SiO2, CH2Cl2), crystd. (acetone/hexane, -24°C); elem. anal.;
DOI:10.1021/ja00266a012

Reference yield: 76.0%

: 82582-46-5
(η5-C5H5)Re(NO)(PPh3)(COCH3)

: 4111-54-0
lithium diisopropyl amide

: 93304-78-0
(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

Guidance literature:: With methyl iodide; In tetrahydrofuran; Re-complex was reacted with ligand in THF at -78°C for 5 min, followed by CH3I;
DOI:10.1021/ja00336a062

Reference yield: 38.0%

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 93304-78-0
(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃)

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; acetic anhydride; In tetrahydrofuran; hexane; under dry N2; soln. of Re complex in THF is cooled to -78°C, addn. of TMEDA followed by soln. of n-BuLi (2 equiv) in hexane; stirred for20 min, addn. of (CH3CO)2O, kept for 25 min. at -24°C; solvents removed under oil pump vac. at room temp., chromd. (SiO2, CH2Cl2);
DOI:10.1021/ja00266a012