1-(4-bromophenyl)-2-ferrocenylacetylene

Base Information

Chemical Name:1-(4-bromophenyl)-2-ferrocenylacetylene
CAS No.:238099-24-6
Molecular Formula:C₁₈H₁₃BrFe
Molecular Weight:365.052
Hs Code.:

Synonyms:1-(4-bromophenyl)-2-ferrocenylacetylene

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Chemical Property of 1-(4-bromophenyl)-2-ferrocenylacetylene

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Technology Process of 1-(4-bromophenyl)-2-ferrocenylacetylene

There total 6 articles about 1-(4-bromophenyl)-2-ferrocenylacetylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1271-47-2
ferroceneacetylene

: 589-87-7
1,4-bromoiodobenzene

: 238099-24-6
1-(4-bromophenyl)-2-ferrocenylacetylene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; In tetrahydrofuran; at 50 ℃; for 3h;
DOI:10.1021/acs.organomet.9b00232

Reference yield: 75.0%

: 1271-47-2
ferroceneacetylene

: 2297-64-5
p-bromophenylsulfonyl hydrazide

: 238099-24-6
1-(4-bromophenyl)-2-ferrocenylacetylene

Guidance literature:: With copper(II) acetate hydrate; 1,3-bis-(diphenylphosphino)propane; palladium diacetate; In N,N-dimethyl-formamide; at 100 ℃; for 0.5h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.joc.7b00899

Reference yield: 41.0%

: 102-54-5,55404-68-7
ferrocene

: 766-96-1
4-bromo-1-ethynylbenzene

: 238099-24-6
1-(4-bromophenyl)-2-ferrocenylacetylene

Guidance literature:: With iron trichloride; copper(II) acetate monohydrate; oxygen; In dichloromethane; acetic acid; ferrocene (3 mmol), CH2Cl2, AcOH, FeCl3 (0.75 mmol), Cu(OAc)2*H2O (0.5 mmol), 4-BrC6H4CCH (3 mmol) mixed, stirred for 1 h at ambient temp., 1.5 h under reflux (75 °C), cooled, Cu(OAc)2*H2O (1.0 mmol), 4BrC6H4CCH (3 mmol) added, stirred for 19.5 h; poured into aq. soln. of ascorbic acid and EDTA disodium salt dihydrate,extracted with CH2Cl2, washed with H2O, dried over Na2SO4, filtered, so lvent removed under vac., column chromd. on silicagel (eluent - petroleum ether-C6H6, 9:1).; elem. anal.;
DOI:10.1016/j.jorganchem.2010.09.039