bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

Base Information

Chemical Name:bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene
CAS No.:437984-78-6
Molecular Formula:C₉₅H₉₈Cl₂Mn₂N₈O₅
Molecular Weight:1612.66
Hs Code.:

Synonyms:bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

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Chemical Property of bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

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Technology Process of bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

There total 1 articles about bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

: 6156-78-1
manganese (II) acetate tetrahydrate

: 7647-14-5
sodium chloride

: 437984-78-6
bis(chloromanganese(III)) 4,5-bis[(2,3,13,17-tetraethyl-3,7,12,18-tetramethyl-15-(2,6-dimethoxyphenyl)-5-porphyrinyl)]-9,9-dimethylxanthene

Guidance literature:: With air; In N,N-dimethyl-formamide; under N2; mixt. of ligand and Mn salt in DMF refluxed in air for 3 h; cooled to room temp.; taken to dryness; taken up in CH2Cl2-water; org. layer sepd.; washed (H2O); stirred with mixt. of satd. aq. NaCl and HCl for90 min; org. layer decanted; solvent removed under vac.; purified by column chromy. (silica gel, CH2Cl2, MeOH-CH2Cl2); retreated with aq. NaCl and HCl; org. phase sepd.; washed (H2O); dried (Na2SO4); taken to dryness; recrystd. from CH2Cl2-ether; elem. anal.;
DOI:10.1021/ic025507k