Pt(p-CF₃Ph)₂(cod)

Base Information

• Chemical Name: Pt(p-CF₃Ph)₂(cod)
• CAS No.: 90478-98-1
• Molecular Formula: C₂₂H₂₀F₆Pt
• Molecular Weight: 593.471
• Mol file: 90478-98-1.mol

Synonyms:Pt(p-CF₃Ph)₂(cod)

Chemical Property of Pt(p-CF₃Ph)₂(cod)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(p-CF₃Ph)₂(cod)

There total 1 articles about Pt(p-CF₃Ph)₂(cod) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 4-(trifluoromethyl)phenylmagnesium bromide (402-51-7) → Pt(p-CF3Ph)2(cod) (90478-98-1)

Guidance literature:

With ammonium chloride; In diethyl ether; 4-CF3C6H4MgBr was added to soln. (COD)PtCl2 in ether, was stirred at room temp. for 12 h under inert atm.; aq. NH4Cl was added, ether layer was dried over MgSO4, filtered through Celite and carbon, and evapd., residue was recrystd. from CH2Cl2/pentane;

DOI:10.1021/ja0480365

Reference yield: 96.0%

Pt(p-CF3Ph)2(cod) (90478-98-1) + diphenylphosphane (829-85-6) → cis-[Pt(C6H4-p-CF3)2(PHPh2)2] (1174291-84-9)

Guidance literature:

In hexane; byproducts: C8H12; (N2); std. Schlenk technique; P ligand was added to soln. of Pt complex in hexane; stirred at room temp. for 1 h; filtered; washed (hexane); dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2009.03.009

Reference yield: 94.0%

Pt(p-CF3Ph)2(cod) (90478-98-1) + 2-chloro-1,3-dimethyl-1,3,2-diazaphospholidine (6069-36-9) → cis-[Pt(p-CF3Ph)2{P(Cl)(NMeCH2)2}2]

Guidance literature:

In benzene; at 25 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c6dt02314b

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

4-(trifluoromethyl)phenylmagnesium bromide

Downstream raw materials:

[Pt(bis(di-tert-butylphosphino)methane)(4-(trifluoromethyl)phenyl)2]

cis-[Pt(C₆H₄-p-CF₃)2(PH(i-Bu)2)2]

cis-[Pt(C₆H₄-p-CF₃)2(PH(t-Bu)2)2]

cis-[Pt(C₆H₄-p-CF₃)2(PHPh₂)2]

Refernces