triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

Base Information

Chemical Name:triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane
CAS No.:1335028-95-9
Molecular Formula:C₂₁H₃₄O₃Si
Molecular Weight:362.585
Hs Code.:

Synonyms:triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

Suppliers and Price of triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

There total 1 articles about triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 994-30-9
triethylsilyl chloride

: 203926-60-7
(2R,3S)-1-(4-Methoxy-benzyloxy)-2-methyl-hex-5-yn-3-ol

: 1335028-95-9
triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; for 0.5h;
DOI:10.1002/anie.201101741

Reference yield: 99.0%

: 1335028-95-9
triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

: 102716-67-6
(3R,6S)-3-(benzyloxy)-6-(((R)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one

: 1335028-96-0
(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((R)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

Guidance literature:: triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.666667h;

(3R,6S)-3-(benzyloxy)-6-(((R)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

With water; ammonium chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1002/anie.201101741

Reference yield: 83.0%

: 1335029-09-8
(3R,6S)-3-(benzyloxy)-6-(((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one

: 1335028-95-9
triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

: 1335029-14-5
(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

Guidance literature:: triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.666667h;

(3R,6S)-3-(benzyloxy)-6-(((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

With water; ammonium chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1002/anie.201101741