1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Base Information

Chemical Name:1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine
CAS No.:116438-02-9
Molecular Formula:C₂₀H₂₁NO₄
Molecular Weight:339.391
Hs Code.:

Synonyms:1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

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Chemical Property of 1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

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Technology Process of 1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

There total 4 articles about 1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 116438-01-8
1-benzyl-6,9-dimethyl-2,5,7,8-tetraoxo-1,2,3,4,5,6,7,8-1-benzazocine

: 116438-02-9
1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; for 0.5h;
DOI:10.1021/jo00257a031

Reference yield:

: 116437-99-1
8-amino-1-benzyl-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

: 116438-02-9
1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: Multi-step reaction with 3 steps

1: 40 percent / CH₂Cl₂ / 0.25 h / 0 °C

2: 95 percent / 60percent aq. perchloric acid / tetrahydrofuran; CH₂Cl₂ / 0.17 h / 0 °C

3: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 0.5 h

With perchloric acid; hydrogen; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; ethyl acetate;
DOI:10.1021/jo00257a031

Reference yield:

: 116438-00-7
8-(acetylimino)-1-benzyl-6,9-dimethyl-2,5,7-trioxo-1,2,3,4,5,6,7,8-1-benzazocine

: 116438-02-9
1-benzyl-7,8-dihydroxy-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / 60percent aq. perchloric acid / tetrahydrofuran; CH₂Cl₂ / 0.17 h / 0 °C

2: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 0.5 h

With perchloric acid; hydrogen; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; ethyl acetate;
DOI:10.1021/jo00257a031