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o-methyl benzoyl ferrocene

Base Information
  • Chemical Name:o-methyl benzoyl ferrocene
  • CAS No.:89670-17-7
  • Molecular Formula:C18H16FeO
  • Molecular Weight:304.171
  • Hs Code.:
o-methyl benzoyl ferrocene

Synonyms:o-methyl benzoyl ferrocene

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Chemical Property of o-methyl benzoyl ferrocene
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Technology Process of o-methyl benzoyl ferrocene

There total 1 articles about o-methyl benzoyl ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With aluminum (III) chloride; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.joc.5b01548
Guidance literature:
In methanol; method from Neshvad, G., Roberts, R. M. G., Silver, J., J. Organomet. Chem., 236(1982), 237; elem. anal.;
DOI:10.1016/S0022-328X(00)99481-6
Guidance literature:
With -CH2-CH[C(C6H5)2]-O-B(CH3)-N-CH2-CH2- (bicyclic); In tetrahydrofuran; Ar atmosphere, addn. of soln. of Fe complex and BH3*SMe2 simultaneously to soln. of bicyclic CBS catalyst at 0°C (30 min), stirring (30 min); >99% ee;
DOI:10.1002/(SICI)1521-3773(19990201)38:3<379::AID-ANIE379>3.0.CO;2-Y
upstream raw materials:

ferrocene

ortho-toluoyl chloride

Downstream raw materials:

ferrocenyl(2-methylphenyl)methanol

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