N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide

Base Information

• Chemical Name: N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide
• CAS No.: 1277175-99-1
• Molecular Formula: C₂₀H₂₈BrNO₃
• Molecular Weight: 410.351
• Mol file: 1277175-99-1.mol

Synonyms:N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide

Chemical Property of N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide

There total 1 articles about N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,3-bis(pent-4-enyloxy)aniline (935431-27-9) + 2-bromoisobutyric acid bromide (20769-85-1) → N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide (1277175-99-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 1.5h;

DOI:10.1002/ejoc.201001367

Reference yield: 86.0%

N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide (1277175-99-1) + 1-amino-2,7-bis(hex-5-enyloxy)naphthalene → 2-[2,7-bis(hex-5-enyloxy)naphthylamino]-N-[2,6-bis(pent-4-enyloxy)phenylamino]-2-methylpropanoylamide

Guidance literature:

With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 17h; Inert atmosphere;

DOI:10.1002/ejoc.201300830

Reference yield: 80.0%

N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide (1277175-99-1) + N-[2,6-bis(pent-4-enyloxy)phenyl]-2-[2,7-bis(pent-4-enyloxy)naphthylamino]-2-methylpropanamide (1277176-00-7) → 2-[2,7-bis(pent-4-enyloxy)naphthylamino]-3-[2,6-bis(pent-4-enyloxy)phenylamino]-2-methylpropane (1277176-01-8)

Guidance literature:

N-[2,6-bis(pent-4-enyloxy)phenyl]-2-[2,7-bis(pent-4-enyloxy)naphthylamino]-2-methylpropanamide; With lithium aluminium tetrahydride; In tetrahydrofuran; for 16h; Reflux;

N-[2,6-bis(pent-4-enyloxy)phenyl]-2-bromo-2-methylpropanamide; In tetrahydrofuran; mineral oil; at 20 ℃; for 18h;

DOI:10.1002/ejoc.201001367

upstream raw materials:

1,3-bis(pent-4-enyloxy)aniline

2-bromoisobutyric acid bromide

Downstream raw materials:

N-[2,6-bis(pent-4-enyloxy)phenyl]-2-[2,7-bis(pent-4-enyloxy)naphthylamino]-2-methylpropanamide

3-[2,7-bis(pent-4-enyloxy)naphthyl]-1-[2,6-bis(pent-4-enyloxy)phenyl]-4,4-dimethyl-4,5-imidazolinium chloride

2-[2,7-bis(pent-4-enyloxy)naphthylamino]-3-[2,6-bis(pent-4-enyloxy)phenylamino]-2-methylpropane