zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

Base Information

Chemical Name:zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)
CAS No.:102425-06-9
Molecular Formula:C₄₈H₃₅BrN₄OZn
Molecular Weight:829.126
Hs Code.:

Synonyms:zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

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Chemical Property of zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

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Technology Process of zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

There total 1 articles about zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.5%

: 110-52-1
1,4-dibromo-butane

: 110275-59-7
meso‐5‐((4‐hydroxyphenyl)‐10,15,20‐tris(phenyl)porphyrinato)zinc(II)

: 102425-06-9
zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; mixt. of Zn-complex, C4H8Br2 and K2CO3 suspended in dry DMF, stirred for48 h at room temp.; solvent evapd. under redused pressure, residue dissolved (CHCl3), washed(H2O), org. layer dried (anhyd. Na2SO4), evapd. to remove solvent, resi due purified by chromy. (silica gel, CHCl3), first fraction collected, concd., purifn. repeated twice;
DOI:10.1021/jp0347419

Reference yield: 71.2%

: 102425-06-9
zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

: 768-94-5
1-Adamantanamine

: 943962-96-7
zinc(II)(5-(4-(ω-(1-adamantaneamino)butyloxy)phenyl)-10,15,20-triphenylporphyrinate)

Guidance literature:: In ethanol; chloroform; High Pressure; soln. (C2H5OH:CHCl3=1:1 v/v) of Zn-complex and 1-adamantanamine in autoclave heated at 100°C for 10 h; solvent removed, residue extd. with 5 % Na2CO3 and CHCl3, org. layer purified over silica gel column with CHCl3/CH3OH (15:1, v/v); elem. anal.;
DOI:10.1021/jp0347419

Reference yield:

: 5-(4-hydroxyphenyl)-10,15,20-tris-(4-methylphenyl)porphyrin

: 102425-06-9
zinc(II)(5-(4-(ω-bromobutyloxy)phenyl)-10,15,20-triphenylporphyrinate)

: Zn(C₄₄H₂₇N₄)O(CH₂)4O(C₄₇H₃₅N₄)

Guidance literature:: In N,N-dimethyl-formamide; stirring of Zn-porphyrin and monohydroxy porphyrin in basic DMF for 1 week;; repeated chromy. (alumina); analysis by reverse-phase h.p.l.c.;;
DOI:10.1039/F29868200219