o-Nitrosophenol

Base Information

• Chemical Name: o-Nitrosophenol
• CAS No.: 13168-78-0
• Molecular Formula: C6H5 N O2
• Molecular Weight: 123.111
• UNII: U90H9A00OR
• Nikkaji Number: J1.405.239I,J668.383E
• Mol file: 13168-78-0.mol

Synonyms:o-nitrosophenol;2-nitrosophenol;Phenol, 2-nitroso-;Orthonitrosophenol;13168-78-0;U90H9A00OR;UNII-U90H9A00OR;2-nitroso-phenol;1,2-benzoquinoneoxime;SCHEMBL431918;SCHEMBL9724748

Chemical Property of o-Nitrosophenol

Chemical Property:

• XLogP3: 1.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 123.032028402
• Heavy Atom Count: 9
• Complexity: 105

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: Many nitroso compounds are carcinogens. Explodes when heated or on contact with "> x. See also NITROSO COMPOUNDS." target="_blank">Many nitroso compounds are carcinogens. Explodes when heated or on contact with

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)N=O)O

Technology Process of o-Nitrosophenol

There total 25 articles about o-Nitrosophenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

(2-hydroxyphenyl)mercury chloride (90-03-9) → o-nitrosophenol (13168-78-0)

Guidance literature:

With nitrosylchloride; In tetrachloromethane; for 1h;

Reference yield:

phenol (108-95-2,27073-41-2) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + p-nitrosophenol (104-91-6) + o-nitrosophenol (13168-78-0) + 2-hydroxynitrobenzene (88-75-5,78813-12-4)

Guidance literature:

With nitric acid; sodium nitrite; at 25 ℃; Product distribution;

Reference yield:

2-amino-phenol (95-55-6) → o-nitrosophenol (13168-78-0)

Guidance literature:

With dihydrogen peroxide; CpMo(CO)3(CCPh); In tert-butyl alcohol; at 20 ℃; for 12h;

DOI:10.1016/j.tetlet.2008.04.005

upstream raw materials:

benzene

2-amino-phenol

phenol

2-nitrosoanisole

Downstream raw materials:

2-hydroxynitrobenzene

2-phenylbenzo[d]oxazole

(C₆H₄O₂BO)C₆H₄(NO)