1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

Base Information

Chemical Name:1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol
CAS No.:1134635-14-5
Molecular Formula:C₈₆H₁₁₂O₁₆Si₄
Molecular Weight:1514.17
Hs Code.:

Synonyms:1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

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Chemical Property of 1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

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Technology Process of 1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

There total 1 articles about 1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 75-77-4
chloro-trimethyl-silane

: 1134635-13-4
2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

: 1134635-14-5
1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/chem.200802189

Reference yield: 80.0%

: 1134635-14-5
1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

: 100-52-7
benzaldehyde

: 143994-68-7
(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5-tri-O-benzyl-D-myo-inositol

Guidance literature:: 1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol; In dichloromethane; at 20 ℃; for 1h; Molecular sieve; Inert atmosphere;

benzaldehyde; With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -40 - -10 ℃;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; water; at -10 - 0 ℃; regioselective reaction;
DOI:10.1002/chem.200802189

Reference yield: 72.0%

: 1134635-14-5
1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

: 100-52-7
benzaldehyde

: 1228177-00-1
4,5-di-O-benzyl-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

: 143994-68-7
(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5-tri-O-benzyl-D-myo-inositol

Guidance literature:: 1,3,4,5-tetrakis(trimethylsilyl)-2,6-di-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol; benzaldehyde; With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 - 20 ℃; Molecular sieve; Inert atmosphere;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; at -20 - 0 ℃; regioselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1021/ol1008137