(EtMe4C5)Re(η2-S3)Cl2

Base Information

• Chemical Name: (EtMe4C5)Re(η2-S3)Cl2
• CAS No.: 335000-95-8
• Molecular Formula: C₁₁H₁₇Cl₂ReS₃
• Molecular Weight: 502.567
• Mol file: 335000-95-8.mol

Synonyms:(EtMe4C5)Re(η2-S3)Cl2

Chemical Property of (EtMe4C5)Re(η2-S3)Cl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (EtMe4C5)Re(η2-S3)Cl2

There total 1 articles about (EtMe4C5)Re(η2-S3)Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

sulfur (10544-50-0) + [(EtC5Me4)ReCl2(η2-1,2-ethanedithiolato)] (461393-06-6) → (EtMe4C5)Re(η2-S3)Cl2 (335000-95-8) + [(EtC5Me4)Re(η2-1,2-ethanedithiolato)(S(x))] + [(EtC5Me4)ReCl2(η2-1,2-ethenedithiolato)] (461393-11-3) + hydrogen sulfide (7783-06-4)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: H2S; (N2); using Schlenk techniques; dissolving of (EtC5Me4)ReCl2(SCH2CH2S) in toluene-d8, filtration, placing into NMR tube, freezing, evacuating, addn. of large excess of S8, degassing, sealing, heating to 70°C for several days; identification by NMR; Kinetics;

DOI:10.1021/ja020125z

Reference yield:

(EtMe4C5)Re(η2-S3)Cl2 (335000-95-8) + hydrogen (1333-74-0) → hydrogenchloride (7647-01-0,15364-23-5) + ((EtMe4C5)Re)2(μ-S)4 + hydrogen sulfide (7783-06-4)

Guidance literature:

In chloroform-d1; complex dissolved in CDCl3, degassed, H2 added at -196°C, sealed,warmed to room temp., monitored by NMR for days; not isolated;

DOI:10.1021/om000962e

upstream raw materials:

sulfur

[(EtC5Me4)ReCl2(η2-1,2-ethanedithiolato)]

Downstream raw materials:

hydrogenchloride

hydrogen sulfide