Aluminate(3-),hexahydro-, potassium (1:3), (OC-6-11)-

Base Information

• Chemical Name: Aluminate(3-),hexahydro-, potassium (1:3), (OC-6-11)-
• CAS No.: 17083-63-5
• Molecular Formula: AlH₆*3K
• Molecular Weight: 150.324
• Mol file: 17083-63-5.mol

Synonyms:Aluminate(3-),hexahydro-, tripotassium (8CI); Aluminate(3-), hexahydro-, tripotassium,(OC-6-11)- (9CI); Potassium hexahydroaluminate (7CI); Aluminum potassiumhydride (AlK3H6); Tripotassium hexahydroaluminate; Tripotassiumhexahydroaluminate(3-)

Chemical Property of Aluminate(3-),hexahydro-, potassium (1:3), (OC-6-11)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: After storage, dry samples have exploded violently when disturbed. When heated"> 2O. See also ALUMINUM COMPOUNDS." target="_blank">After storage, dry samples have exploded violently when disturbed. When heated

MSDS Files:

Useful:

Technology Process of Aluminate(3-),hexahydro-, potassium (1:3), (OC-6-11)-

There total 3 articles about Aluminate(3-),hexahydro-, potassium (1:3), (OC-6-11)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium aluminium hydride → tripotassium hexahydroaluminate (17083-63-5) + hydrogen (1333-74-0) + potassium hydride + aluminium (7429-90-5)

Guidance literature:

In solid; pyrolysis KAlH4;

Reference yield:

potassium aluminium hydride + potassium hydride → tripotassium hexahydroaluminate (17083-63-5)

Guidance literature:

In Dimethyl ether; N2 or Ar; NaH and NaAlH4 (2:1 molar ratio) mixed at -40°C, sealed, heated to 80 and 160°C for 12 h; XRD;

DOI:10.1016/j.ica.2007.04.044

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + potassium hydride → potassium aluminium hydride + tripotassium hexahydroaluminate (17083-63-5) + potassium chloride

Guidance literature:

In melt; mixt. of LiAlH4, KH and TiCl3 in 1:2:0.04 mol ratio made by dry mixing, ball-milled for 40 min, molten state processed at 170 °C under H2pressure of 4500 psi for 2 h;

DOI:10.1016/j.jpcs.2008.03.021

upstream raw materials:

lithium aluminium tetrahydride

Refernces

• 1、 Santhanam, Ranganathan,Sean McGrady. "Synthesis of alkali metal hexahydroaluminate complexes using dimethyl ether as a reaction medium". . p. 473 - 478. Retrieved 2008.