ZINC MESO-TETRAPHENYLPORPHINE

Base Information

• Chemical Name: ZINC MESO-TETRAPHENYLPORPHINE
• CAS No.: 14074-80-7
• Molecular Formula: C44H28 N4 Zn
• Molecular Weight: 678.123
• Hs Code.: 29339900
• Wikidata: Q27122470
• ChEMBL ID: CHEMBL2373168,CHEMBL2373103
• Mol file: 14074-80-7.mol

Synonyms:Porphine,a,b,g,d-tetraphenyl-, Zn deriv. (6CI);Zinc, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; Zinc, [5,10,15,20-tetraphenylporphinato(2-)]- (8CI); Zinc, [a,b,g,d-tetraphenylporphinato(2-)]-(7CI); 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, zinc complex;(5,10,15,20-Tetraphenyl-21H,23H-porphinato)zinc;(5,10,15,20-Tetraphenylporphine)zinc; (5,10,15,20-Tetraphenylporphyrinato)zinc;(5,10,15,20-Tetraphenylporphyrinato)zinc(II); (Tetraphenylporphyrinato)zinc;(meso-Tetraphenylporphinato)zinc; 5,10,15,20-Tetraphenylporphinatozinc;Tetraphenylporphinato zinc; Tetraphenylporphinatozinc(II); Tetraphenylporphinezinc chelate; Tetraphenylporphyrin zinc complex; Tetraphenylporphyrinzinc(II);Zinc meso-tetraphenylporphyrin; Zinc tetraphenylporphine; Zinctetraphenylporphyrin; Zinc(II)tetraphenylporphyrin; Zinc,5,10,15,20-tetraphenyl-21H,23H-porphine;[5,10,15,20-Tetraphenylporphinato(2-)]zinc; meso-(Tetraphenylporphyrinato)zinc

Chemical Property of ZINC MESO-TETRAPHENYLPORPHINE

Chemical Property:

• Appearance/Colour: purple crystalline powder
• Melting Point: >350 °C (decomp)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 34.58000
• Density: g/cm³
• LogP: 6.43530
• Storage Temp.: −20°C
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 676.160539
• Heavy Atom Count: 49
• Complexity: 807

Purity/Quality:

98%,99%, ^*data from raw suppliers

Zinc(II) Tetraphenylporphyrin >98.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): UN NO.
• Hazard Codes: UN NO.
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C9=CC=CC=C9)[N-]3.[Zn+2]
• Uses: A porphyrin used in light emitting diodes. It has valuable biological applications in molecular biology, fluoroimmunoassay and new pharmaceutical developments.

Technology Process of ZINC MESO-TETRAPHENYLPORPHINE

There total 83 articles about ZINC MESO-TETRAPHENYLPORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

zinc(II) acetate dihydrate (5970-45-6) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → zinc tetraphenylporphyrin (14074-80-7)

Guidance literature:

In methanol; chloroform; for 0.5h; Reflux;

DOI:10.1016/j.molstruc.2017.09.091

Reference yield: 99.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + zinc(II) acetate dihydrate (5970-45-6) → zinc tetraphenylporphyrin (14074-80-7)

Guidance literature:

In methanol; chloroform; tetraphenylporphyrin (300 mg) and Zn(OAc)2*2H2O (800 mg) refluxed (1 h) in CHCl3/MeOH (2:1); cooled; solvent removed (vac.); dissolved in CHCl3; chromd. (silica, CHCl3);

DOI:10.1021/jp061844t

Reference yield: 94.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → zinc tetraphenylporphyrin (14074-80-7)

Guidance literature:

With zinc diacetate; In methanol; chloroform; for 1h;

DOI:10.1039/c0cc01972k

upstream raw materials:

5,15,10,20-tetraphenylporphyrin

5,10,15,20-tetraphenyl-21H,23H-porphine

zinc(II) acetate dihydrate

zinc diacetate

Downstream raw materials:

5,10,15,20-tetraphenylporphyrine dihydrochloride

(tetraphenylporphyrin)zinc chloride cation radical

tetrabutylammonium (tetraphenylporphyrin)zinc chloride

Zn 5,10,15,20-tetraphenylporphyrin monoanion

Refernces

• 1、 He, Chao,He, Qingguo,Deng, Changmin,Shi, Liqi,Zhu, Defeng,Fu, Yanyan,Cao, Huimin,Cheng, Jiangong. "Turn on fluorescence sensing of vapor phase electron donating amines via tetraphenylporphyrin or metallophenylporphrin doped polyfluorene". . p. 7536 - 7538. Retrieved 2010.
• 2、 Saini, G. S. S.,Chaudhury, N. K.,Verma, A. L.. "Laser-power-dependent Coordination and Photo-oxidation of Zinc Tetraphenylporphin in Alkyl Chlorides probed by Resonance Raman Spectroscopy". . p. 2853 - 2858. Retrieved 1992.
• 3、 Liu, Biao,Mirkin, Michael V.. "Electron transfer at liquid/liquid interfaces. The effects of ionic adsorption, electrolyte concentration, and spacer length on the reaction rate". . p. 3933 - 3940. Retrieved 2002.
• 4、 Cissell, Julie A.,Vaid, Thomas P.,Yap, Glenn P. A.. "The doubly oxidized, antiaromatic tetraphenylporphyrin complex [Li(TPP)][BF4]". . p. 2401 - 2404. Retrieved 2006.
• 5、 Rojas-Montoya, Sandra M.,Vonlanthen, Mireille,Porcu, Pasquale,Flores-Rojas, Gabriel,Ruiu, Andrea,Morales-Morales, David,Rivera, Ernesto. "Synthesis and photophysical properties of novel pyrene-metalloporphyrin dendritic systems". . p. 10435 - 10447. Retrieved 2019.
• 6、 D'yakonov, Vladimir A.,Dzhemilev, Usein M.,Dzhemileva, Lilya U.,Halder, Nyancy,Ramazanov, Ilfir R.,Rath, Harapriya. "Comparative in vitro Studies of the Topoisomerase I Inhibition and Anticancer Activities of Metallated N-Confused Porphyrins and Metallated Porphyrins". . . Retrieved 2020.
• 7、 Takeda, Yoshihiko,Takahara, Shigeru,Kobayashi, Yoshiko,Misawa, Hiroaki,Sakuragi, Hirochika,Tokumaru, Katsumi. "Isoporphyrins. Near-Infrared Dyes with Noticeable Photochemical and Redox Properties". . p. 2103 - 2106. Retrieved 1990.
• 8、 Atoyebi, Adewole O.,Brückner, Christian. "Observations on the Mechanochemical Insertion of Zinc(II), Copper(II), Magnesium(II), and Select Other Metal(II) Ions into Porphyrins". . p. 9631 - 9642. Retrieved 2019.
• 9、 Perrier,Gauthier,Dao. "SPECTRAL COSENSITIZATION IN PHTHALOCYANINE-PORPHYRIN PHOTOELECTROCHEMICAL CELLS.". . p. 598 - 602. Retrieved 1988.
• 10、 Obaleye, Joshua A.,Tella, Adedibu C.,Obiyenwa, Gabriel K.,Simon, Nzikahyel,Olawale, Margaret D.. "Zinc(II) Complex of Meso-Tetraphenylporphyrin with 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II)". . p. 589 - 595. Retrieved 2016.